Photoacoustic spectroscopy (PAS) can be utilized as an ultrasensitive gas detection method. The basic principles of gas detection using PAS are discussed in this paper. First, the basic instrumentation for a PAS gas detection system is introduced focusing on the photoacoustic cell. The discussion includes non-resonant photoacoustic cells and the different types of resonant photoacoustic cells, including the longitudinal photoacoustic cell, the Helmholtz photoacoustic cell, the T-type photoacoustic cell, and the high-frequency resonant photoacoustic cell. The basic working principles of each of these, cells as well as the advantages and disadvantages of photoacoustic cells are discussed, and the development of newer types of photoacoustic cells in recent years is outlined in detail. This review provides detailed reference information and guidance for interested researchers who would like to design and build advanced photoacoustic cells for gas detection.
ViengerovM.L.. “New Method of Gas Analysis Based on Tyndall-Roentgen Optoacoustic Effect”. Dokl. Akad. Nauk. SSSR. 1938. 19: 687–688.
3.
KerrE.AtwoodJ.. “The Laser Illuminated Absorptivity Spectrophone: A Method for Measurement of Weak Absorptivity in Gases at Laser Wavelengths”. Appl. Opt. 1968. 7(5): 915–921.
4.
DongwookK.YuL.RadenkaM.. “Ammonia Gas Sensors: A Comprehensive Review”. Talanta. 2019. 204: 713–730.
5.
SekharP.K.WignesF.. “Trace Detection of Research Department Explosive (RDX) Using Electrochemical Gas Sensor”. Sens. Actuators, B. 2016. 227: 185–190.
6.
LiuX.F.DongH.P.XiaS.H.. “Micromachined Catalytic Combustion Type Gas Sensor for Hydrogen Detection”. Micro Nano Lett. 2013. 8(10): 668–671.
7.
BarriaultM.AlexanderI.TasnimN.O’BrienA.NajjaranH., et al. “Classification and Regression of Binary Hydrocarbon Mixtures Using Single Metal Oxide Semiconductor Sensor with Application to Natural Gas Detection”. Sens. Actuators, B. 2020. 326: 129012. https://doi.org/10.1016/j.snb.129012
8.
YangT.H.ChenW.G.WangP.Y.. “A Review of All-Optical Photoacoustic Spectroscopy as a Gas Sensing Method”. Appl. Spectrosc. Rev. 2021. 56(2): 143–170.
9.
BolshovM.A.KuritsynY. A.RomanovskiiY. V.. “Tunable Diode Laser Spectroscopy as a Technique for Combustion Diagnostics”. Spectrochim. Acta, Part B. 2015. 106: 45–66.
10.
TyasF.H.NikitaJ.G.Apriyanto, MitrayanaD.K.AminM.N.. “The Performance of CO2 Laser Photoacoustic Spectrometer in Concentration Acetone Detection as Biomarker for Diabetes Mellitus Type”. J. Phys.: Conf. Ser. 2018. 1011(1): 012056. https://doi.org/10.1088/1742-6596/1011/1/012056
11.
NavasM.J.JiménezA.M.AsueroA.G.. “Human Biomarkers in Breath by Photoacoustic Spectroscopy”. Clin. Chim. Acta. 2012. 413(15–16): 1171–1178.
12.
C.M. Popa, M.N. Verga, M. Patachia, B.S. George, et al. “Advantages of Laser Photoacoustic Spectroscopy in Radiotherapy Characterization”. Rom. Rep. Phys. 2014. 66(1): 120–126.
13.
DanC.D.PetrusM.BratuA.M.PopaC.. “Applications of Near Infrared Photoacoustic Spectroscopy for Analysis of Human Respiration: A Review”. Molecules. 2020. 25(7): 1728.
14.
DumitrasD.C.DutuD.C.MateiC.CernatR., et al. “Evaluation of Ammonia Absorption Coefficients by Photoacoustic Spectroscopy for Detection of Ammonia Levels in Human Breath”. Laser Phys. 2011. 21(4): 796–800.
15.
PopaC.. “Infrared Spectroscopy Study of the Influence of Inhaled Vapors/Smoke Produced by Cigarettes of Active Smokers”. J. Biomed. Opt. 2015. 20(5): 051003. https://doi.org/10.1117/1.JBO.20.5.051003
16.
SchmithausenA.J.TrimbornM.BüscherW.. “Methodological Comparison Between a Novel Automatic Sampling System for Gas Chromatography Versus Photoacoustic Spectroscopy for Measuring Greenhouse Gas Emissions Under Field Conditions”. Sensors. 2016. 16(10): 1638. https://doi.org/10.3390/s16101638
YinX.DongL.WuH.ZhangL.MaW., et al. “Highly Sensitive Photoacoustic Multicomponent Gas Sensor for SF6 Decomposition Online Monitoring”. Opt. Express. 2019. 27(4): A224–A234.
19.
LinharesF.G.LimaM.A.MotheG.A.de CastroM.P.P.da SilvaM.G., et al. “Photoacoustic Spectroscopy for Detection of N2O Emitted from Combustion of Diesel/Beef Tallow Biodiesel/Sugarcane Diesel and Diesel/Beef Tallow Biodiesel Blends”. Biomass Conv. Bioref. 2019. 9(3): 577–583.
20.
ShahG.A.ShahG.M.RashidM.I.GrootJ.C.J.TraoreB., et al. “Bedding Additives Reduce Ammonia Emission and Improve Crop N Uptake After Soil Application of Solid Cattle Manure”. J. Environ. Manage. 2018. 209: 195–204.
21.
YinX.DongL.WuH.ZhengH.MaW., et al. “Sub-ppb Nitrogen Dioxide Detection with a Large Linear Dynamic Range by Use of a Differential Photoacoustic Cell and a 3.5 W Blue Multimode Diode Laser”. Sens. Actuators, B. 2017. 247: 329–335.
22.
EliaA.FrancoC.D.SpagnoloV.LugaràP.M.ScamarcioG.. “Quantum Cascade Laser-Based Photoacoustic Sensor for Trace Detection of Formaldehyde Gas”. Sensors. 2009. 9(4): 2697–2705.
23.
YiH.LiuK.ChenW.TanT.WangL., et al. “Application of a Broadband Blue Laser Diode to Trace NO2 Detection Using off-Beam Quartz-Enhanced Photoacoustic Spectroscopy”. Opt. Lett. 2011. 36(4): 481–483.
JinQ.. Optimal Design of Photoacoustic Cell for Wavelength Modulated Photoacoustic Detection System. [Master of Science Dissertation]. Dalian, China: Dalian University of Technology, 2016.
26.
D.C. Dumitras, D.C. Dutu, C. Matei, A.M. Magureanu, et al. “Laser Photoacoustic Spectroscopy: Principles, Instrumentation, and Characterization”. J. Optoelectron. Adv. Mater. 2007. 9(12): 3655–3701.
27.
KarbachA.HessP.. “High Precision Acoustic Spectroscopy by Laser Excitation of Resonator Modes”. J. Chem. Phys. 1985. 83: 1075–1084.
28.
BessonJ.-P.. Photoacoustic Spectroscopy for Multi-Gas Sensing Using Near Infrared Lasers. [Doctor of Science Thesis]. Lausanne, Switzerland: Ecole Polytechnique Federale de Lausanne, 2006.
29.
JiangY.ChenT.YuanH.ZhangY., et al. “Application of Nonresonant Photoacoustic Cavity in Fire Detection”. J. Appl. Sci. 2006. 24(6): 623–626.
30.
LiY.. Research on Transformer DGA Technology Based on Photoacoustic Spectroscopy. [M.S. Dissertation]. Harbin, China: Harbin Institute of Technology, 2007.
31.
LiY.ZhaoX.. “Dissolved Gas Monitoring System in Transformer Oil Based on Photoacoustic Spectroscopy”. Sens. Microsyst. 2011. 30(6): 103–105.
32.
ZhangW.. Research on Photoacoustic Spectroscopy Trace Gas Detection Technology and Its Application. [Ph.D. Dissertation]. Dalian, China: Dalian University of Technology, 2010.
33.
HuangM.. Research on SF6 Concentration Detection Method Based on Differential Absorption Photoacoustic Spectroscopy. [M.S. Dissertation]. Hubei, China: Hubei University of Technology, 2020.
34.
LuftK. F.. “Uber Eine Neue Methode der Registrierenden Gasanalyse Mit Hilfe der Absorption Ultraroter Strahlen Ohne Spektrale Zerlegung”. Z. Med. Phys. 1943. 24: 97–104.
35.
MohebbifarM.R.. “High-Sensitivity Detection and Quantification of CHCl3 Vapors in Various Gas Environments Based on the Photoacoustic Spectroscopy”. Microw. Opt. Technol. Lett. 2019. 61(9): 2234–2241.
36.
ShenC.ZhangY.NiJ.. “Development and Application of Optical Gas Absorption Cell in Absorption Spectroscopy”. Infrared. 2012. 33(12): 1–7.
37.
ZhangM.. Research on Key Technologies of Trace Gas Detection by Near Infrared Photoacoustic Spectroscopy. [M.S. Dissertation]. Dalian, China: Dalian University of Technology, 2018.
38.
ZhangM.ZhangB.ChenK.GuoM.LiuS., et al. “Miniaturized Multi-Pass Cell Based Photoacoustic Gas Sensor for Parts-per-Billion Level Acetylene Detection”. Sens. Actuators. A. 2020. 308(3): 112013. https://doi.org/10.1016/j.sna.2020.112013
39.
WangZ.XieS.LiJ.. “Simulation Design of a New Optical Long-Range Absorption Cell”. Phys. Exp. Coll. [Daxue Wuli Shiyan]. 2016. 29(3): 74–79.
40.
RobertC.. “Simple, Stable, and Compact Multiple-Reflection Optical Cell for Very Long Optical Paths”. Appl. Opt. 2007. 46(22): 5408–5418.
41.
ChenK.ZhangB.LiuS.JinF.GuoM., et al. “Highly Sensitive Photoacoustic Gas Sensor Based on Multiple Reflections on the Cell Wall”. Sens. Actuators. A. 2019. 290: 119–124.
42.
YinQ.WangT.QianM.. Photoacoustic and Photothermal Technology and Its Applications [Guāng shēng guāngrè jìshù jí qí yìngyòng]. Beijing, China: Science Press, 1991.
43.
DeweyC.F.RogerD.K.HackettC.E.. “Acoustic Amplifier for Detection of Atmospheric Pollutants”. Appl. Phys. Lett. 1973. 23(11): 633–635.
44.
KreuzerL.. “Ultralow Gas Concentration Infrared Absorption Spectroscopy”. J. Appl. Phys. 1971. 42(7): 2934–2943.
45.
MiklósA.HessP.BozókiZ.. “Application of Acoustic Resonators in Photoacoustic Trace Gas Analysis and Metrology”. Rev. Sci. Instrum. 2001. 72(4): 1937–1955.
46.
GerlachR.AmerN.M.. “Brewster Window and Windowless Resonant Spectrophones for Intracavity Operation”. Appl. Phys. 1980. 23(3): 319–326.
47.
NodovE.. “Optimization of Resonant Cell Design for Optoacoustic Gas Spectroscopy (H-Type)”. Appl. Opt. 1978. 17(7): 1110–1119.
48.
RückT.BierlR.MatysikF.M.. “Low-Cost Photoacoustic NO2 Trace Gas Monitoring at the pptV-Level”. Sens. Actuators. A. 2017. 263: 501–509.
49.
ChengG.CaoY.LiuK.CaoY.-N.ChenJ.-J., et al. “Numerical Calculation and Optimization of Photoacoustic Cell in Photoacoustic Spectroscopy Detection Device”. Acta Phys. Sin. 2019. 68(7): 074202. https://doi.org/10.7498/aps.68.20182084
50.
LiZ.YangC.TangZ.PengM.WenjunN., et al. “Design and Performance Analysis of Curved Waist Photoacoustic Cell”. China Laser. 2021. 48(1): 186–195.
51.
WolffM.KostB.BaumannB.. “Shape-Optimized Photoacoustic Cell: Numerical Consolidation and Experimental Confirmation”. Int. J. Thermophys. 2012. 33: 1953–1959. https://doi.org/10.1007/s10765-012-1257-2
KinslerL.E.FreyA.R.CoppensA.B.. Fundamentals of Acoustics. New York, USA: Wiley, 2001.
54.
TavakoliM.TavakoliA.TaheriM.SaghafifarH.. “Design, Simulation and Structural Optimization of a Longitudinal Acoustic Resonator for Trace Gas Detection Using Laser Photoacoustic Spectroscopy (LPAS)”. Opt. Laser Technol. 2010. 42(5): 828–838.
55.
GongZ.ChenK.ChenY.MeiL.YuQ.. “Integration of T-Type Half-Open Photoacoustic Cell and Fiber-Optic Acoustic Sensor for Trace Gas Detection”. Opt. Express. 2019. 27(13): 18222–18231.
56.
CaoY.LiuQ.WangR.LiuK., et al. “Development of a 443 nm Diode Laser-Based Differential Photoacoustic Spectrometer for Simultaneous Measurements of Aerosol Absorption and NO2”. Photoacoustics. 2021. 21: 100229. https://doi.org/10.1364/OE.27.018222
YinX.GaoM.MiaoR.SuY., et al. “High Sensitivity Carbon Monoxide Gas Sensor Based on Differential Photoacoustic Cell Structure (Specially Invited)”. Acta Photonica Sin. 2021. 50(10): 1030002. https://doi.org/10.3788/gzxb20215010.1030002
59.
LiuL.HuanH.LiW.MandelisA.WangY., et al. “Highly Sensitive Broadband Differential Infrared Photoacoustic Spectroscopy with Wavelet Denoising Algorithm for Trace Gas Detection”. Photoacoustics. 2021. 21: 100228. https://doi.org/10.1016/j.pacs.2020.100228
60.
G.R. Lima, L. Mota, A. Miklós, J. Angster, Z. Dubovski, et al. “Sensitive Harmonic Detection of Ammonia Trace Using a Compact Photoacoustic Resonator at Double-Pass Configuration and a Wavelength-Modulated Distributed Feedback Diode Laser”. Appl. Phys. B: Lasers Opt. 2014. 117(1): 333–341.
61.
BijnenF.G.C.ReussJ.HarrenF.J.M.. “Geometrical Optimization of a Longitudinal Resonant Photoacoustic Cell for Sensitive and Fast Trace Gas Detection”. Rev. Sci. Instrum. 1996. 67(8): 2914–2923.
62.
LiuK.MeiJ.ZhangW.ChenW.GaoX.. “Multi-Resonator Photoacoustic Spectroscopy”. Sens. Actuators, B. 2017. 251: 632–636.
63.
ChenK.ChenY.ZhangB.MeiL.GuoM., et al. “Highly Sensitive Photoacoustic Microcavity Gas Sensor for Leak Detection”. Sensors. 2020. 20(4): 1164. https://doi.org/10.3390/s20041164
64.
GongZ.ChenK.YangY.ZhouX.YuQ.. “Photoacoustic Spectroscopy Based Multi-Gas Detection Using High-Sensitivity Fiber-Optic Low-Frequency Acoustic Sensor”. Sens. Actuators, B. 2018. 260: 357–363.
65.
MiklósA.PeiS.KungA.. “Multipass Acoustically Open Photoacoustic Detector for Trace Gas Measurements”. Appl. Opt. 2006. 45(11): 2529–2534. https://doi.org/10.1364/AO.45.002529
66.
ZhaS.MaH.ZhaC.CaiX.LiY., et al. “Trace Gas Detection Based on Photoacoustic Spectroscopy in 3D Printed Gas Cell”. J. Near Infrared Spectrosc. 2020. 28(4): 236–242.
67.
RouxelJ.CoutardJ. G.GidonS.LartigueO.NicolettiS., et al. “Development of a Miniaturized Differential Photoacoustic Gas Sensor”. Procedia Eng. 2015. 120: 396–399.
68.
MaD.. “Development of Helmholtz Resonator”. Physics. 1993. 22(8): 452–456.
69.
ZhaoY.FangY.LiY.LiD.. “Design and Optimization of Multi Gas Detector for Helmholtz Photoacoustic Spectroscopy”. Infrared Laser Eng. [Hóngwài Hé Jīguāng Gōngchéng]. 2017. 46(6): 130–138.
70.
ShiB.HuK.. “Design of Helmholtz Resonance Photoacoustic Cell”. J. Zhejiang Univ. 1985. 2(19): 79–89.
71.
SongG.YaoH.. “Study on Gas Infrared Laser Photoacoustic Spectroscopy”. J. South China Univ. Technol. (Nat. Sci. Ed.). 1988. 3: 65–75.
72.
RouxelJ.CoutardJ.G.GidonS.LartigueO.NicolettiS., et al. “Miniaturized Differential Helmholtz Resonators for Photoacoustic Trace Gas Detection”. Sens. Actuators, B. 2016. 236: 1104–1110.
73.
FernandesJ.KangS.MannoorM.. “Numerical Comparative Study on the Performance of Open Photoacoustic Cells”. J. Mech. Sci. Technol. 2021. 35(4): 1473–1485.
74.
ParvitteB.RisserC.VallonR.ZéninariV.. “Quantitative Simulation of Photoacoustic Signals Using Finite Element Modelling Software”. Appl. Phys. B. 2013. 111(3): 383–389.
75.
GerasA.StareckiT.. “Parametric Analysis of a Differential Photoacoustic Helmholtz Cell”. Int. J. Thermophys. 2014. 35(12): 2269–2278.
76.
AlahmariS.KangX.HipplerM.. “Diode Laser Photoacoustic Spectroscopy of CO2, H2S and O2 in a Differential Helmholtz Resonator for Trace Gas Analysis in the Biosciences and Petrochemistry”. Anal. Bioanal. Chem. 2019. 411(17): 3777–3787.
77.
StareckiT.GerasA.. “Differential Open Photoacoustic Helmholtz Cell”. Int. J. Thermophys. 2014. 35(12): 2259–2268.
78.
LiQ.HuY.. “Influence of Structural Parameters of Helmholtz Resonator on Amplification Performance”. In: Proceedings of 2008 National Acoustic Academic Conference; Shanghai; 22–24 October 2008. Vol. 10. Pp. 36–37.
79.
RisserC.ParvitteB.VallonR.ZeninariV.. “Optimization and Complete Characterization of a Photoacoustic Gas Detector”. Appl. Phys. B. 2015. 118(2): 319–326.
80.
V. Zeninari, R. Vallon, C. Risser, B. Parvitte. “Photoacoustic Detection of Methane in Large Concentrations with a Helmholtz Sensor: Simulation and Experimentation”. Int. J. Thermophys. 2016. 37(1): 1–11. https://doi.org/10.1007/s10765-015-2018-9
81.
BaumannB.KostB.GroningaH.WolffM.. “Eigenmode Analysis of Photoacoustic Sensors via Finite Element Method”. Rev. Sci. Instrum. 2006. 77(4): 044901. https://doi.org/10.1063/1.2186808
82.
KostB.BaumannB.WolffM.GroningaH.. “Towards the Optimization of Photoacoustic Sensors”. Paper presented at: 10th International Conference on Optimum Design in Engineering. Lisbon, Portugal; 11–13 July 2022. Vol.91, Issue10. Pp. 97–107. https://doi.org/10.2495/OP070101
83.
MannoorM.KangS.. “Numerical Analysis of a ‘T’ Type Resonant Photoacoustic Cell”. Paper presented at: 2016 International Conference on Computational Modeling, Simulation, and Applied Mathematics. Bangkok, Thailand; 24–25 July 2016. Pp. 313–316. https://doi.org/10.12783/dtcse/cmsam2016/3625
84.
NiuM.LiuQ.WangG.YuanY., et al. “Research and Application of Low Temperature Performance of T-Type Photoacoustic Cell”. Spectrosc. Spectral Anal. [Guangpuxue Yu Guangpu Fenxi]. 2013. 33(3): 577–581.
85.
BaumannB.WolffM.TeschnerM.. “Open Photoacoustic Cell for Blood Sugar Measurement: Numerical Calculation of Frequency Response”. ArXiv. 2015. 15(7): 05189. https://doi.org/10.48550/arXiv.1507.05189
86.
J. Kapp, C. Weber, K. Schmitt, H. F. Pernau, J. Wöllenstein. “Resonant Photoacoustic Spectroscopy of NO2 with a UV-LED Based Sensor”. Sensors. 2019. 19(3): 724. https://doi.org/10.3390/s19030724
87.
LiuL.HuanH.AndreasM.ShaoX.. “Quantitative Detection of Dissolved Gas in Multicomponent Transformer Oil by Fourier Transform Infrared Photoacoustic Spectroscopy”. Spectrosc. Spectral Anal. [Guangpuxue Yu Guangpu Fenxi]. 2020. 40(3): 684–687.
88.
ZhangL.LiuL.ZhangX.YinX., et al. “T-type Cell Mediated Photoacoustic Spectroscopy for Simultaneous Detection of Multi-Component Gases Based on Triple Resonance Modality”. Photoacoustics. 2023. 31: 100492. https://doi.org/10.1016/j.pacs.2023.100492
89.
ShiQ.HuS.ChenJ.HaoL., et al. “A Novel Spherical Photoacoustic Cell With High Performance Laser Photoacoustic Spectroscopy: Theoretical and Experimental Study”. J. Chem. Phys. 1998. 1: 20–25.
JingH.PengL.FanY.WangD., et al. “Development of Detection Device for SF6 Decomposition Components Based on Photoacoustic Spectroscopy”. J. Electr. Eng. 2014. 7: 42–46.
92.
YuX.LiZ.LiuJ.FangY.SiG., et al. “Research on Gas Detection by Photoacoustic Spectroscopy Based on Integrating Sphere Gas Chamber”. Acta Opt. Sin. 2021. 41(16): 120–127. https://doi.org/10.3788/AOS202141.1612002
93.
PengY.. Research on Photoacoustic Detection Technology of Trace Gas Based on Tunable Fiber Laser. [Ph.D. Dissertation]. Dalian, China: Dalian University of Technology, 2011.
94.
ZhangC.QiaoS.MaY.. “Highly Sensitive Photoacoustic Acetylene Detection Based on Differential Photoacoustic Cell with Retro-Reflection-Cavity”. Photoacoustics. 2023. 30: 100467. https://doi.org/10.1016/j.pacs.2023.100467
95.
ManninenA.TuzsonB.LooserH.BonettiY.EmmeneggerL.. “Versatile Multipass Cell for Laser Spectroscopic Trace Gas Analysis”. Appl. Phys. B. 2012. 109(3): 461–466. https://doi.org/10.1007/s00340-012-4964-2
