Surface-active amine polymerization accelerators can be prepared by the reaction of poly-epoxy resins with the sodium salt of N-phenylglycine and N-methyl-p-toluidine. These materials are expected to promote adhesion through complexation with surface calcium (or other metal ions), utilizing several chelating groups per molecule, and by functioning as polymerization accelerators for dental resins; they can also function as catalysts for the anionic polymerization of cyanoacrylate monomers.
Get full access to this article
View all access options for this article.
References
1.
Retief, D.H. : Laboratory Evaluation of the Tensile Adhesive Bond Strength of a Composite Dental Restorative System Containing a Surface-Active Comonomer to Enamel and Dentine, J Dent Ass S Afr30:595-6011975.
2.
Bowen, R.L.: Surface-Active Comonomer and Method of Preparation. U. S. Patent3,200,142 (Aug. 10, 1965) .
3.
Bowen, R.L.: Investigation of the Surfaces of Hard Tooth Tissues by a Surface Activity Test, Proceedings of the Workshop on Adhesive Restorative Dental Materials at Indiana University, Sept. 28-29, 1961.
4.
Bowen, R.L.: Adhesive Bonding of Various Materials to Hard Tooth Tissues. II. Bonding to Dentin promoted by a Surface-Active Comonomer, J Dent Res44:895, 1965.
5.
Bowen, R.L.: Adhesive Bonding of Various Materials to Hard Tooth Tissues. III. Bonding to Dentin Improved by Pretreatment and the Use of a Surface-Active Comonomer , J Dent Res44:903, 1965.
6.
Bowen, R.L.: Adhesive Bonding of Various Materials to Hard Tooth Tissues. IV. Bonding to Dentin, Enamel, and Fluorapatite Improved by the Use of a Surface-Active Comonomer, J Dent Res44:906, 1965.
7.
Bowen, R.L.: Adhesive Bonding of Various Materials to Hard Tooth Tissues. V. The Effect of a Surface-Active Comonomer on Adhesion to Diverse Substrates, J. Dent Res44:1369, 1965.
8.
Chandler, H.H. ; Bowen, R.L.; Paffen-Barger , G.C.; and Mullineaux, A.L.; Clinical Evaluation of a Radiopaque Composite Restorative Material After Three and One Half Years, J Dent Res52:1128, 1973.
9.
Misra, D.N., and Bowen, R.L.: Adhesive Bonding of Various Materials to Hard Tooth Tissues. XI. Chemisorption of the Adduct of Diglycidyl Ether of Bisphenol A with N-phenylglycine on Hydroxyapatite , J Phys Chem80:842, 1977.
10.
Misra, D.N., and Bowen, R.L.: Adhesive Bonding of Various Materials to Hard Tooth Tissues. XII. Adsorption of N- (2-hydroxy-3 - methacryloxypropyl) - N - phenylglycine [NPG-GMA] on Hydroxyapatite, in preparation.
11.
Bowen, R.L. : Adhesive Bonding of Various Materials to Hard Tooth Tissues. IX. The Concept of Polyfunctional Surface - Active Comonomers , J Biomed Mater Res9 :501-510, 1975.
12.
Shechter, L. ; Wynstra, J.; and Kurkjy, R.P.: Glycidyl Ether Reactions with Amines, Ind Eng Chem48:94-97, 1956.
13.
Lee, H., and Neville, K.: Handbook of Epoxy Resins, New York: McGraw-Hill Book Co., 1967, chap 4, pp 3, 44, 59.
14.
Simons, W.A. , and Zanger, M.: The Sadtler Guide to NMR Spectra of Polymers , Philadelphia : Sadtler Research Laboratories, Inc., 1973.
15.
Bowen, R.L.: Properties of a Silica-Reinforced Polymer for Dental Restorations , JADA66:57, 1963.
16.
Bowen, R.L., and Argentar, H.: Tertiar Aromatic Amine Accelerators with Molecular Weights Above 400 , J Dent Res51:473, 1972.
17.
Sato, T.; Kita, S.; and Otsu, T.: A Study on Initiation of Vinyl Polymerization with Diacyl Peroxide-Tertiary Amine Systems by Spin Trapping Technique, Die Makromolekulare Chemie176:561-571, 1975.
18.
Plueddemann, E.P., and Stark, G.L.: Silane Coupling Agents for Alumina Trihydrate , Proceedings of the 31st Annual Conference , Feb 3-6, New York: Soc Plastics Ind Inc. , 1976, J Phy Chem 80:842, 1977.
19.
Bowen, R.L.; Chandler, H.H.; Misra, D.N.; and Wycoff, H. 0. : Additional Studies of Metal-filled Resin Composites , in preparation.
