Abstract
Measurement devices such as sweating manikins, cylinders or hotplates are used for testing thermal and moisture transfer properties of clothing or textiles. A critical feature of these measurement devices is the design of the outer covering fabric that tightly enfolds the device like a skin. The artificial skin principally has to match individual requirements because the different sweating devices have different sweating systems and surface compositions. In this study knitted fabrics with different fiber and yarn types are proposed to be used as an artificial skin. Thermal and moisture properties of the fabrics were measured to obtain skin-like characteristics and a mathematical model for the quantification of thermal and moisture-management properties based on geometrical characteristics was developed. The results show that the thermal and moisture-management properties of the fabrics do not only depend on the fiber properties but also relevantly on their geometrical properties such as thickness, diameter and number of stitch pores. For example, thermal resistance is significantly affected by the stitch pore diameter, and evaporative resistance by the fabric thickness. Furthermore, water content and drying speed are determined by the capillary structure, and therefore, are more influenced by yarn and fabric structure parameters, whereas contact angle and wettability are more influenced by the fiber type. In conclusion, the tested fabrics satisfy all the requirements to match the anatomical properties of the human skin; however, two fabric types, PES_19f30_SET and PES_28f48_GL, exhibited superior characteristics suitable for application as artificial skin on measurement devices.
According to international standards and scientific literature, there is a variety of measurement devices used for the investigation of thermodynamic processes in textiles and clothing, such as radiation, conduction, convection, moisture evaporation. 1 As a common basic principle, these thermodynamic measurement devices simulate the metabolic heat loss. A critical feature of such measurement devices is the design of the outer covering fabric that is tightly enfolding the device like a skin. These fabrics are not standardized and a great variety of materials and designs are currently used.
Most common thermodynamic measurement devices for textile and clothing are alambeta and permetest,2,3 guarded hotplates,4–6 thermal cylinders7,8 and thermal manikins.9–11 They comprise a great variety of materials, such as metals (copper, aluminum, bronze)4,11,12 or polymers,13,14 flexible material such as membranes, woven or knitted fabrics,4,15,16 paintings or coatings12,17 as their surface finish. The analysis of the literature shows that there are no consistent standards addressing the surface finish.4,11,18–21 Beside their surface finish many thermal manikins are additionally covered by fabric skin.14,22 Sweating guarded hotplates are commonly covered by a vapor permeable PTFE-membrane combined with a hydrophobic woven PES-fabric according to the standard DINCEN/TR16422-2012. 23
The thermodynamic properties of the fabric skins are assessed by measurement devices such as the Moisture Management Tester (MMT) or the heat and mass loss method according to ASTM F 2370. 22 Different knitted fabrics (cotton, polyester and hydrophilic polyester) used as artificial skin for manikins have been investigated with regards to moisture transfer property measured on fully wetted skin. 24 In some cases such as thermo-physiological human simulators, transient measurements with regards to temperature and sweat rate are also applied. To be able to evaluate the behavior of the fabrics in different phases of sweating (onset of wetting, fully developed sweating and drying) four fabrics (cotton with elastane, polyester, polyamide with elastane and fabric skin provided by manikin manufacturer Thermetrics) have been investigated by Koelblen et al. 25 Findings of the study showed similarly good performance for the three tested fabrics, however, the recommendation was to choose the type of fabric that best meets the requirements of the sweating system. For the wetting phase, the spreading of a homogeneous liquid on the fabric’s surface is proposed to guarantee the cooling effect as at the human skin. For evaporative resistance measurements, according to standards, a high moisture content with a low drying rate is suggested to ensure a sufficiently steady state to take measurements.
The ability of knitted fabrics to transport heat and mass depends on the fiber properties and the porosity of the yarn and fabric structure. Wetting is determined by the fiber surface and the wetting liquid, whereby the wicking process is mostly affected by the capillaries between the fibers and yarns, thus, by the arrangement of the fibers in yarns and in knitted fabrics. Therefore, the pore size and number of pores in a fabric’s structure are crucial parameters in determining its thermodynamic properties.26,27 The fabric pore structure also influences further physical properties such as thermal conductivity, capillary flow by the use of intermolecular forces between the liquid and surrounding fiber surfaces, water adsorption within yarn pores and the ability of hygroscopic fibers to swell.28–31
Research groups investigated how thermal resistance strongly correlates with thickness, mass per unit area and porosity in fabrics related to air entrapped in the fabric structure, 32 and that the amount of water wicked from inside to the outer surface strongly correlates with thickness and pore size.29,33
The geometrical properties of the fabrics used as artificial skin have to match the anatomical properties of the human skin to simulate a human’s heat and mass release realistically by using thermodynamic devices.
The human skin interacts between the body and the environment as a multilayer interface to regulate temperature and therefore heat and mass transport. 34 The human skin’s outermost hydrophobic layer, the epidermis, is made up of horny cells, and suet and sweat glands. 35 Its thickness varies between 0.05 ∼ 1.2 mm 36 and it is estimated to have the ability to contain a water amount of 72% of its skin weight. 37 The thermal conductivity λ of the skin varies between 0.5 and 2.8 W m−1 K−1 depending on blood circulation and moisture in the hydrophilic body tissue. 38 The human skin’s moisture permeability of 0.003 W m−2 Pa−2 is the inverse of evaporative resistance Re. 39 Moisture evaporates through sweat glands to the skin’s surface. Sweat glands have an average diameter of 0.4 µm and an average pore number of about 120 per square centimeter depending on the body segment. 36 The insensible water loss defines the measured quantity of water passing from inside the body through the epidermis to the ambient atmosphere via diffusion and evaporation processes and depends on several anatomical factors such as anatomical site and thickness or others such as lipid content, blood flow or skin temperature. 34 The daily insensible water loss for humans (surface area 1.8 m2) varies between 0.6 and 2.3 l, hands and feet losing the most (50–160 g h-1), the head and neck losing 40–75 g h−1 and all remaining other parts between 15–60 g h−1. 40 The capacity for the active secretion of sweat is very large, whole-body sweat losses can exceed more than 2 l h−1 during physical activity, 41 with rates of about 3–4 l h−1 during intense exercising in the heat for short durations. 42
In this study, different knitted structures were developed to get skin-like thermal properties to be used as an artificial skin in a relaxed state for thermal measurement devices. For this purpose the designed knitted fabrics were developed to match anatomical properties of the human skin, such as a thickness between 0.05 ∼ 1.2 mm, a pore size of 400 µm and number of pores about 120 cm−2. Different fiber and yarn types were selected and characterized with regards to pores in knitted fabrics and their influence on measured heat and mass transfer in different sweating phases (wetting, fully developed sweating and drying). Additionally, a functional model was developed using multiple regression analysis and correlations to investigate the relationship between geometrical and heat and mass transfer properties particularly in fabric skins.
The fabric skin as a potential artificial skin for sweating thermal devices was recommended by performing systematic studies to get the best match with human skin.
Symbols and abbreviations for the most important technical terms
Methods
Pore size calculation
To determine the geometrical properties of the knitted fabrics, such as thickness ht [mm], stitch pore diameter (pore size) dptt [µm] and number of stitch pores nptt, the entire pore structure in the fabric [cm3 m−2] was computed based on the pore and fiber volume [cm3 m−2] in individual yarns and in knitted fabrics. 43 The entire pore structure in the fabric consists of meso-pores occurring between the fibers in the yarn and makro-pores occurring between interconnected yarns in the fabric that are known as stitch pores. Physical parameters of fibers, such as density ρt [g cm−3] and the fineness mf [dtex] of yarns such as diameter dy [µm] and fineness my [tex], and of fabrics such as mass mt [g m−2] and thickness ht [mm], were measured. The yarn end-fineness myn [dtex] is the product of the fineness my [tex] and number of yarns ny.
The specific volume of the fabric Vt is the reciprocal mathematical function of the density ρt which was calculated according to Equation 1 and is an important value for the characterization of the fiber and pore volume in the fabric:
To characterize the pore structure in the fabrics, the pore and fiber volume [cm3] were calculated for a fabric area of 1 m2 and to a yarn length of 10 km. For determining the volume ratio from fibers to pores, the fabric volume Vt [cm3 m−2] was calculated as follows:
The yarn volume Vyt in the knitted fabric [cm3 m−2] results from the product of the yarn volume Vy [cm3 10 km−1] as a result of the yarn fineness my [dtex] divided by the yarn density ρy [g cm−3]. The yarn length in the knitted fabric lyt [km m−2] results from the mass of fabrics mt [g m−2] and yarn end-fineness myn [dtex]:
The product of the fiber volume in yarn Vfy [cm3 10 km−1] and yarn length in the knitted fabric lyt [km m−2] is the fiber volume in the textile Vft [cm3 m−2]:
The pore volume Vpyt in the fabric [cm3 m−2] results from the product of the yarn pore volume Vpy [cm3 10 km−1] and yarn length in the fabric lyt [km m−2]. The pore volume in yarn Vpy [cm3 10 km−1] is calculated by multiplying the yarn volume Vy [cm3 10 km−1] by the relative pore volume in the yarn Vpyr [%], which is the result of the yarn density ρy [g cm−3] divided by the fiber density ρf [g cm−3] minus 1:
By subtracting the fiber volume Vft [cm3 m−2] from the total volume Vt [cm3 m−2] the total pore volume Vpt [cm3 m−2] of the knitted fabric is calculated as follows:
The stitch pore volume Vptt [cm3 m−2] is calculated analogous to the total pore volume Vpt [cm3 m−2] included in the knitted fabrics:
To summarize, the sum of the pore and fiber volume [cm3 m−2] results in the entire fabric volume balance Vtt [cm3 m−2] as,
The number of stitch pores
Given the assumption that all stitch pores are cylindrical with a circular cross-section, the equivalent pore diameter dptt [µm] can be calculated as follows:
Selection of yarns
Characterization of yarn types
GL (flat), SET (fixed), HE (highly extensible)
The fiber types included natural or synthetic fibers with varying length as staple fiber and continuous fibers as filaments. The number of filaments varied between 30 and 104 (e.g. f30 in Table 2). The labeling also marks the applied texturing processes. The addition GL indicates total oriented yarns with a characteristically low elastic and volumetric quality (non-textured filament yarns). The additions SET and HE indicate drawn-textured yarns or fully drawn yarns with a medium elastic/volumetric quality (SET) or a high elastic/volumetric quality (HE), respectively (textured filament yarns). The yarn fineness my is specified in the unit [tex].
Manufacturing weft knitted fabrics
Preliminary manufacturing tests were conducted on the knitting machine for a great variety of knitting structures to meet the geometrical properties of human skin (thickness ht, stitch pore diameter dptt and number of pores nptt) and ensure mechanical stability. Therefore, different machine settings such as needle gauge, number of stitches in wales and course-direction, knitting structure and sinking depth were altered and provided crucial parameters for the knitting process to achieve the fabric geometrical properties desired for mimicking the human skin. The selected 18 weft knitted fabrics matched the requirements of the human skin structure with defined thickness ht, stitch pore diameter dptt and number of pores nptt.
The 14 different yarn types were used to manufacture the 18 weft knitted fabrics on a flatbed knitting 12-gauge machine (type: STOLL CMS330.6 TC). The machine was set to knit 200 stitches in wales (x) and 400 stitches in course-direction (y), so all fabrics were comprised of precisely the same number of stitches or stitch pores. The fabrics were manufactured in double knit structure (both needle beds activated) to obtain a 1 × 1 rib structure. The smallest sinking depth as the specific parameter number given by the knitting machine manufacturer (dimensionless number 8.3) was used on this type of flatbed knitting machine to manipulate the loop length and stitch density and achieve the desired geometrical values such as thickness ht and stitch pore diameter dptt. Eleven fabrics were knitted using the single yarns and seven fabrics were knitted using the double yarn described as the number of yarns ny and marked with an ending ‘2’ in Table 4. For statistical reasons, all knitted fabrics were reproduced three times and a sample was cut out of each fabric.
After knitting, all fabrics received standard care by washing (easy-care washing program, washing temperature of 40℃, 1000 U min−1) according to the standard EN ISO 6330-2001. 44 Human skin is hydrophobic at the surface, however, in order to be able to measure mass transfer, the surface has to be fully wetted, therefore the fabric skin has to be hydrophilic. To assess the wettability of fabrics, a simple test was performed by dripping a water droplet on the fabric’s surface from a syringe. The eight fabrics made of the fiber types PES and CV turned out to be highly hydrophobic and were additionally treated by using a padding machine (Mathis, Switzerland), an aqueous polymer solution ARRISTAN AIR (CHT, Germany) and a lab dryer (Mathis, Switzerland) to turn them into hydrophilic specimens as required for the artificial skin.
Experimental design
The size in width and length of all washed and hydrophilic-treated fabrics were measured to define the stitch pore number nptt, whereby the total number of counted stitch pores (wales multiplied by course-direction) is divided by the measured fabric area m2. The mass mt according to EN 1212745 and thickness ht according to ISO 5084 46 of the fabric were measured and the end-fineness of yarns myn was calculated by multiplying the yarn fineness my according to EN ISO 2060 47 by the number of yarns ny. In addition, the pore volumes were calculated as outlined before.
Thermal and wicking properties related to the behavior of the fabrics in different sweating phases, such as onset of wetting, fully developed sweating and drying were measured in the knitted fabrics. The thermal properties, such as conductivity λ and thermal resistance Rct were determined to evaluate the thermal parameters. These properties are relevant to calculate the thermal resistance Rc of the air layer on the device for reference measurements or of the tested fabric or clothing sample. Since the sensors of the (sweating) guarded hotplate or manikins are actually under the skin, the temperature on the outer side of the skin is lower than that on the sensors. By using thermal parameters, further measurements can be corrected. The evaluation of onset of wetting was indicated by the contact angle θ between liquid and surface and by the water spreading ability on fabrics investigated by the MMT. Therefore, wetting and wicking are influenced by the yarn structure and contact angle. Information about the wetting and wicking properties in fabrics is provided by measuring the time t that is needed to moisten the fabric successively from top to the bottom. The shape of water spot occurring on the bottom surface, determined by measuring the diameter of the spot r, provides information about water spreading ability. The role of evaporative resistance Ret was to allow sufficient evaporation from within the fabric and from its surface, since evaporation takes place in the entire thickness of the fabric in its pores. The maximum water content was determined to evaluate fabric behavior in the fully developed sweating phase. The drying speed DS is a basic indication of fabric behavior in the drying phase. For thermal devices, the surface area is one of the crucial parameters and therefore both properties, maximum water content WC and drying speed DS, are provided in relation to surface named as surfacial maximum water content SWC or surfacial drying speed SDS. All fabric samples were conditioned for 12 hours at the required environmental conditions (temperature of 20 ± 0.5℃ and relative humidity of 65 ± 5%). Tap water was used to pre-wet fabric samples. 25
Evaluation of thermal and moisture properties on the artificial skins
Thermal conductivity
The instrument KALCOS was used for measuring conductivity according to standard DIN 52612 48 at an air temperature of 20 ± 0.5℃ and relative humidity of 65 ± 5%. Each fabric sample with the dimensions of 20 x 20 cm was placed in-between the measuring plates under a defined temperature gradient of 5℃ (upper plate 25℃, lower plate 20℃, normal pressure 2 kPa). The heating power at steady state (maintained for at least 30 min) was measured and the sample’s thermal conductivity λ (W m−1 K−1) was calculated. The fabric thickness ht needed for the thermal conductivity calculation was determined using a thickness meter (Universal Micrometer, accurate to 1 µm, Frank PTI-GmbH, Germany) at the same normal pressure of 2 kPa that was applied during measurement. 46
Thermal and evaporative resistance
The thermal and evaporative resistances (Rct and Ret) of three samples of each of the fabrics (25 x 25 cm) were determined using a (sweating) guarded hotplate simulating a human’s heat production by metabolism and heat release by conduction, radiation, convection and evaporation. The tests were performed according to ISO 110924 in a climatic chamber at an air temperature of 20 ± 0.5℃, relative humidity of 65 ± 5%, air speed parallel to the sample of 1 ± 0.05 m s−1 for the thermal resistance, and an air temperature of 35 ± 0.5℃, relative humidity of 40 ± 5%, and air speed of 1 ± 0.05 m s−1 for the evaporative resistance.
Contact angle
The contact angle between the fabric surface and water droplet on the fabric was determined by using the drop shape analyzer DSA-25 (Krüss GmbH, Hamburg, Germany) under climate controlled conditions (air temperature of 20 ± 0.5℃, relative humidity of 65 ± 5%). 49 For the tests, a water drop with a volume of 4 µl was applied on three samples measuring 1 x 1 cm with a syringe. A camera recorded the wetting process. The angle between fabric surface and drop contour was measured by digital picture analysis. The maximum measurement time was set to 25 s. Surfaces with contact angles between 0° and 90° are defined to be wettable or hydrophilic and surfaces with contact angles between 90° and 180° are defined to be non-wettable or hydrophobic.
Wetting and wicking
The MMT (M290MMT, SDL Atlas, USA) was used to characterize the wetting and wicking processes in three samples of each fabric (ø 8 cm) at an air temperature of 20 ± 0.5℃, relative humidity of 65 ± 5%, and air speed below 0.1 m s−1. Principally, the time to moisten the fabric sample successively from top to the bottom and the radius of wetted spots were measured. The spreading time for the upper fabric surface was set to 20 s. The results were classified according to the terms of the device manufacturer. 50
Water content and drying speed
The maximal moisture content was determined by weighing the dry fabric samples (10 x 10 cm) and putting them in a water bath at an air temperature of 20 ± 2℃ and relative humidity of 65 ± 5% for four hours. Afterwards, the saturated fabrics were fastened with a clamp on a stand, which was placed on a scale (Mettler AE240-S, accurate to ±0.02 g, Mettler-Toledo, Switzerland) and covered by a shield to prevent weight fluctuation due to air movement in the air-conditioned laboratory. The wet fabrics were observed until water stopped forming drops due to gravitational moisture displacement within the sample and then the actual measurement started. The scale was connected to a computer to record the weight change over time and the total drying time.
Statistical analysis
By using a multiple linear regression model, the relationship between the thermal and wicking properties to the geometrical properties of the fabric were described in the statistical software SPSS (IBM Microsoft, Version 22). This method offers the possibility to assess geometrical properties, their influence on measured heat and mass transfer in different sweating phases and to identify the most influential properties (predictors).
Description of the variables and constants in the model
The relationship type between independent and dependent variables (linear or others) was determined based on scatter plots of the experimental data for individual predictors and was tested statistically:
Results
Physical and thermal properties of fabrics
The results of the measurements of the end-fineness of yarns myn, mass mt, thickness ht and density ρt of the fabrics are presented in Table 4. The calculated numbers nptt and diameter dptt of stitch pores are also presented in Table 4.
Physical properties of the fabrics
_2 implies the number of yarns ny
In order to validate the calculated equivalent diameter dptt and number of stitch pores nptt for a fabric area of 1 cm2, a comparison between the microscopic and graphic display of these geometrical parameters are shown in Figure 1.
Comparison between the microscopic and graphic display of stitch pore diameter dptt and number of stitch pores nptt in manufactured knitted fabrics.
Thermal and moisture properties determined in fabrics
– thermal conductivity; Rct – thermal resistance; Ret – evaporative resistance; θ – contact angle; t – wetting time; r – wetting radius; SWC – surfacial water content; WC – water content; DS – drying speed; SDS – surfacial drying speed.
Thermal conductivity
Fabrics consisting of staple fiber yarns resulted in higher values for thermal conductivity λ compared to fabrics consisting of filament yarns. The fabrics consisting of filament yarn PA66_11f34 textured as HE and SET showed only a difference of about 0.001 W m−1 K−1.
In the fabrics consisting of the yarn PA66_11f34_SET the thermal conductivity λ differed by about 0.004 W m−1 K−1, which was related to the number of yarns ny. In comparison, for the fabrics consisting of non-textured filament yarn PA66_18f104_GL, thermal conductivity λ differed by a five times higher value of about 0.021 W m−1 K−1.
The thermal conductivity λ of human skin is higher by more than one power of ten than that of the fabrics.
Thermal and evaporative resistance
Fabrics made of staple fiber yarns systematically showed values higher than 0.027 m2 K W−1, fabrics made of filament yarns showed values lower than 0.027 m2 K W−1. The double-yarn processed fabrics had lower values for thermal resistance Rct than the single-yarn processed fabrics.
The evaporative resistance Ret ranged between about 2.5 and 6.0 m2 Pa W−1. Particularly, fabrics made of staple fiber yarns showed values higher than about 4.0 m2 Pa W−1, and fabrics made of filament yarns showed values lower than 4.0 m2 Pa W−1, except for PA66_100f26/2, which had a value of 4.30 m2 Pa W−1. The double-yarn processed fabrics had higher values for evaporative resistance Ret than the single-yarn processed fabrics.
Thermal resistance Rct is basically the inverse of thermal conductivity λ. Human skin has different values depending on its blood circulation and moisture compared to the fabrics, which varied between 0.016 and 0.046 m2 K W−1. In comparison to the human skin moisture permeability of 0.003 W m−2 Pa−2, the inverse of the evaporative resistance Ret of the fabric varied in a range between 0.16 and 0.39 W m−2 Pa−2.
Contact angle
In Table 5 it is shown that the treated fabrics made of PES- and CV-fiber and two PA-fiber fabrics (PA66_11f34_HE and PA66_24f48_GL) were highly hydrophilic with contact angles θ of 0°, while the other fabrics were hydrophobic with contact angles θ greater than 90°. Contact angles between 0° and 90° were not observed.
Wetting and wicking
In the top-to-bottom surface wicking process in the tested knitted fabrics, the wetting time of the bottom surface was slightly delayed compared to the top surface (since the water droplets were applied from the top in the MMT device). The hydrophilic fabrics (contact angle θ = 0°) mostly showed a short top-to-bottom wetting time of less than about 5 s. Most of the hydrophobic fabrics (contact angle θ > 100°) showed a wetting time between about 5 and 15 s (medium). The wetting radius on the top and bottom surface of the fabric, respectively, was approximately the same size in both hydrophilic and hydrophobic fabrics. The hydrophilic fabrics (θ = 0°) mostly showed a wetting radius on the bottom between about 15 and 28 mm (large). The wetting radius on hydrophobic fabric surfaces (θ > 100°) was slightly smaller and ranged between about 10 and 15 mm (medium). The hydrophobic fabrics PA66_23f26/2, PA66_11f34_SET and PA66_18f104_GL showed radii smaller than 10 mm. The effect of both transversal and lateral wetting is related to the water affiliation properties of the fabrics (e.g. contact angle) for initial wetting and the capillary forces within the fabric structure for further spreading of the moisture within the fabric. The particular results obtained for the fabrics considered in this study follow this logic consistently.
Water content and drying speed
The maximum surfacial water content SWC was determined and varied between 364 and 971 g m−2 with high standard deviations. The relationship between wetted and dry weight referred to m−2 was derived from determining the water content. The single-yarn processed fabrics showed higher values than double-yarn processed fabrics. Fabrics from textured filament yarns and usually staple fiber yarns showed water content WC values higher than 2.30 g g−1 compared to fabrics from non-textured filament yarns with, unexceptionally, only values smaller than 2.30 g g−1 and thus, maximum water content WC was about three times higher in comparison to human skin with an average of 0.75 g g−1.
The surfacial drying speed SDS of the knitted fabrics varied from 917 to 1713 g m−2 h−1. The fabrics of staple fiber yarns usually had surfacial drying speeds higher and fabrics of filament yarns lower than 1000 g m−2 h−1. The surfacial drying speed SDS decreased by the number of yarns ny.
The daily insensible water loss for humans varying between 22 and 89 g m−2 h−1, exceeding up to 1000 g m−2 h−1 during physical performance, with rates up to about 1600 g m−2 h−1 lies within the same range as the surfacial drying speed SDS of fabrics.
Statistical analysis
The conducted correlations between predictors related to dependent variables are presented in Figure 2, whereby the predictor thickness ht was related to evaporative resistance Ret and drying speed DS showed coefficients of determinations R2 of about and higher than 0.5, also the predictor diameter of stitch pores dptt was related to thermal resistance Rct with an R2 of about 0.5 and RMSD values smaller than the average standard deviation of the given data set.
Correlations between predictors and dependent variables and the corresponding coefficient of determination.
By replacing the sought coefficients a and b, the specific model for thermal resistance Rct, evaporative resistance Ret and drying speed DS was defined and the most influential predictors identified. In all regression models the standard error was very low.
The specific model for thermal resistance Rct was defined as:
The value a2 indicated that as the diameter of stitch pores dptt increased by one unit, thermal resistance Rct increased by
The specific model for evaporative resistance Ret was defined as:
The value a1 indicated that as thickness ht increased by one unit, evaporative resistance Ret increased by 4.48 units. The thickness ht was identified as the most influential predictor (p-value = 0.004). The fit of this multiple regression model was assessed with R2 = 0.62 and root-mean-square deviation RMSD = 0.15 m2 Pa W−1 (the mean standard deviation of measured Ret approximated 0.10 m2 Pa W−1 for Ret values in the range of 2.59–5.92 m2 Pa W−1).
The specific model for drying speed DS was defined as:
The value a1 indicated that as thickness ht increased by one unit, drying speed DS increased by 12.58 units. The thickness ht was identified as the most influential predictor (p-value = 0.002). The predictor number of stitch pores nptt showed a negative value, indicating a negative relationship to the outcome. The fit of this multiple regression model was assessed with R2 = 0.62 and root-mean-square deviation RMSD = 1.3 g h−1 (the mean standard deviation of measured DS approximated 1.1 g h−1 for DS values in the range of 8.9–17.2 g h−1).
Discussion
The geometrical properties of the weft knitted fabrics developed in this study are similar to the anatomical properties of the human skin. In particular, the thickness ht (from 0.90 to 1.20 mm), stitch pore diameter dptt (from 200 to 700 µm) and stitch pore number nptt (from 190 to 360 cm−2) of the knitted fabrics are very similar to the characteristic distribution of thickness between about 0.05 ∼ 1.2 mm, sweat gland number between about 80 and 500 cm−2 or sweat gland diameter of about 400 µm of the human skin. The water content WC of the fabrics varied between 354 and 971 g m−2 (1.46 and 4.77 g g−1), and thus, it was about three times higher in comparison to human skin with an average of 0.75 g g−1. The wetting contact angle θ of the fabrics ranged from 0° (highly hydrophilic) to 180° (highly hydrophobic), whereby the contact angle θ of human skin is averagely 104° (hydrophobic). Interestingly, the tested hydrophobic fabrics PA66_23f26/2 with 129 ± 6°, PA66_11f34_SET with 144 ± 6°, PA66_18f104_GL with 138 ± 22° and PP_20 with 138 ± 31° best met the hydrophobic top layer of human skin (epidermis). Nonetheless, the main interest of this study focuses on the functionality of fabric skin as the imitation of human-like sweating, which implies good moisture spreading properties for efficient skin wetting. In this case the hydrophilic fabrics have a clear advantage to fulfill the expected wetting and wicking performance of the fabric skin. Another unexpected phenomenon was that the fabrics made of PA-fibers expected to be highly hydrophilic turned out to be highly hydrophobic. The different yarn structure and number of yarns in the fabrics might explain the hydrophobicity. 28
The conductivity λ of the fabrics investigated, which ranged from 0.041 to 0.062 W m−1 K−1, increased by the increase of fabric density ρt and had a quantity between air (0.025 W m−1 K−1) and water (0.598 W m−1 K−1) 52 saying that knitted fabrics as porous material mainly consist of pores formed by fibers filled with air or water. The thermal resistance Rct of the fabrics investigated ranged from 0.016 and 0.046 m 2 K W−1 and is basically the inverse of the thermal conductivity, however the thermal resistance values are about five times higher because different measurement conditions such as compression and air movement on fabric influence its surface structure. The thermal resistance Rct of air with 0.022 m2 K W−1 53 had a quantity in the middle of the fabric’s range. The thermal conductivity λ and resistance R as insulation properties are higher by more than one power of ten for the human skin consisting of hydrophilic body tissue and hydrophobic epidermis depending on blood circulation and moisture compared to fabric skins. However, the knitting structure provides geometrical structure to transfer mass for simulating the wicking process.
The thermal properties, such as conductivity λ and thermal resistance Rct, are relevant to calculate the thermal resistance Rc of the air layer on the device for reference measurements or of the tested fabric or clothing sample. Since the sensors of the (sweating) guarded hotplate or manikins are actually under the skin, the temperature on the outer side of the skin is lower than that on the sensors. By using thermal parameters further measurements can be corrected.
The role of evaporative resistance Ret was to allow sufficient evaporation from within a fabric and from its surface since evaporation takes place in the entire thickness of the fabric in its pores. In comparison to a human skin moisture permeability of 0.003 W m−2 Pa−2, the inverse of the evaporative resistance Ret of the fabric varied in a range between 0.16 and 0.39 W m−2 Pa−2.
The wettability of fabrics affects moisture behavior, whereby hydrophilic fabrics (contact angle θ = 0°) show short wetting times and large wetting radii on the bottom of measured fabrics. The cooling effect that occurs on top of human skin is imitated on the bottom of fabric skins where the actual cooling and wetting take place. According to Koelblen et al. 25 the cooling effect shows a desirable characteristic for sweating simulation on fabric skins. They also discussed how measured moisture properties might be different in horizontal and vertical orientations of the measurement surface or skin, and the cooling effect might be smaller when testing samples in a vertical orientation due to water flowing downwards under the influence of gravity, and also forces and couples acting in-between the fibers might manipulate moisture behavior. Therefore, fabric samples with lower downward wetting ranges are recommended due to moisture migration and the dripping of water.
Fabrics from textured filament yarns and usually staple fiber yarns reach a water content based on dry weight higher than 2.30 g g−1, while non-textured filament yarns have a water content based on dry weight lower than 2.30 g g−1. The water content WC is about three times higher in comparison to human skin with an average of 0.75 g g−1. That means that the critical thickness of the water layer on the skin's surface and water droplets start to drip off laying between 364 and 971 g m−2 and are hardly comparable with human skin with about 37.6 g m−2. 54 Due to water on fabrics surface traps inside the fabric skin structure while water on humans’ skin forms droplets and runs off the surface. Also, literature data were given from only one test person, which is not conclusive enough for statistical reliability.
Fabrics made of staple fiber yarns usually show drying speeds higher than fabrics made of filament yarns, and the double-yarn processed fabrics have higher drying speeds in comparison to single-yarn processed fabrics due to the pore structure in yarns and fabrics. The drying speed DS is related to the amount of captured water within the fabric, as human skin is related to the blood circulation and water loss.
The daily insensible water loss for humans varying between 22 and 89 g m−2 h−1, exceeding up to 1000 g m−2 h−1 during physical performance, with rates up to about 1600 g m−2 h−1, lies within the same range as the surfacial drying speed SDS of fabrics varying between 917 and 1593 g m−2 h−1, which indicates that the fabrics ensure continuous wicking and moisture transfer for sweating simulation.
The statistical analysis of measured properties in Figure 2 shows correlations between the geometrical properties such as thickness ht, which are related to evaporative resistance Ret and drying speed DS with coefficients of determinations R2 of about and higher than 0.5, also the diameter of stitch pores dptt is related to thermal resistance Rct with an R2 of about 0.5. Thermal conductivity λ, water content WC, wetting time t and radius r do not correlate with geometrical properties with R2 being below 0.2. And thus, it is not possible to accurately predict these parameters using the geometrical properties because the mean variation is very large. In the resultant regression equations (equations 12–14) the thermal and evaporative resistance Rct and Ret, and drying speed DS of the knitted fabrics are predominantly affected by the most influential geometrical properties, such as thickness ht, diameter of stitch pores dptt and stitch pore number nptt, whereby the p-value smaller than 0.05 proved their significance. The stitch pore diameter dptt significantly contributes to thermal resistance Rct with a coefficient of
The different sweating devices have different sweating systems, e.g. water supply through horizontally oriented porous metal plates, sweat glands distributed on vertically oriented cylindrical shapes or water supply on artificial skin draped on measurement surface. Therefore, the artificial skin properties need to be chosen individually to match the requirements of the specific devices. Furthermore, pre-wetted skins used on non-sweating devices require high water content WC and a low drying speed DS to provide a longer steady state for measuring, whereas a fast drying speed DS and low water content WC are beneficial to mimic artificial skin used on devices including continuous water supply. The requirements are related to thermal properties (conductivity, thermal and evaporative resistance) and moisture behavior (water content, drying speed) investigated on the fabrics, and are influenced by geometrical characteristics and the wettability of the fabrics.
The fabric sample PES_19f30_SET made of fiber polymer PES and textured yarn (FDY) provides highly desirable thermal and moisture-management properties to mimic human skin to be used as pre-wetted artificial skin on measurement devices. The hydrophilic fabric presents low wetting times and a large wetting radius in comparison to a high water content of about 21 g g−1 and a relatively low surfacial drying speed of 1150 g m−2 h−1. However, to mimic human skin for use as artificial skin on measurement devices with a continuous water supply, the fabric type made of non-textured yarn (TOY) is preferred. Therefore, the hydrophilic fabric sample PES_28f48_GL made of fiber polymer PES meets the requirements with low wetting times, a large wetting radius and even a low water content of about 11 g g−1 and related fast surfacial drying speed of 957 g m−2 h−1.
A comparison of the results on proposed fabric skins with existing fabric skins (25) will be subjected to further studies. However, the focus of this study was to create fabrics with specific properties based on the developed theoretical model and in this way, the fabrics’ performance can be improved by changing production parameters.
The authors Postle and Munden55,56 investigated how the fiber and pore structure in relaxed plain-knitted fabrics are influenced by flexural and torsional strains in fibers, which implies a function of force distribution that varies the effective yarn diameter and mesh pore diameter. That approach has not been considered in this study yet because the equivalent pore diameter dptt was calculated from the relevant geometric modeling of knitting structures. Additionally, further investigations are necessary on artificial skins based on weft knitted fabrics fashioned as tight-fitted garments dressed on cylindrically shaped and upright positioned devices, e.g torso or sweating manikin in stretched conditions. Therefore, a redistribution of geometrical characteristics such as stitch pore diameter dptt and thickness ht might occur and affect the thermal and moisture behavior.
Conclusion
The tested fabrics satisfy all the requirements to match the anatomical properties of the human skin, such as thickness, pore size and number of pores, used as artificial skin on measurement devices measuring thermal and moisture properties.
The regression analysis offers the possibility to assess the impact of geometrical properties thickness ht, stitch pore diameter dptt and number of stitch pores nptt on measured heat and mass transfer in different sweating phases and to identify the most influential predictors. The stitch pore diameter dptt significantly increased thermal resistance Rct although with an extremely low value, whereby the thickness ht significantly increased the evaporative resistance Ret and also the drying speed DS. The knitting structure provides geometrical structure to transfer mass for simulating the wicking process.
Two fabric samples are proposed for different types of sweating systems. The fabric sample PES_19f30_SET is considered for the use as artificial skin on measurement devices without any water supply due to its high wettability and potential to absorb and store high amounts of water rapidly in combination with its low drying speed. The fabric sample PES_28f48_GL is recommended for artificial skin on measurement devices with a water supply due to its high wettability and the ability to absorb water rapidly in combination with low water content and related fast drying speed.
Those two ideal fabric samples provide possible alternatives to previously used artificial skin for measurement devices such as guarded hotplates and thermal manikins to determine thermodynamic properties of clothing textiles.
Footnotes
Acknowledgement
The authors wish to thank scientists from BioMemTex at Empa, Dr Emel Mert and Barbara Koelblen for the introduction to and quality assurance of the fabric tests, Dr Agnieszka Dabrowska for consultation on the properties of hydrated human skin. We further acknowledge the support rendered by the scientist from Laboratory Knitting Technology at DITF, Uwe Röder, for the technical development of the knitting fabrics.
Declaration of conflicting interests
The authors declared no potential conflicts of interest with respect to the research, authorship, and/or publication of this article.
Funding
The authors disclosed receipt of the following financial support for the research, authorship, and/or publication of this article: This work was supported by Fundamental Research Funds of the DITF German Institutes of Textile and Fiber Research and Empa Swiss Federal Laboratories for Materials Science and Technology.
