Abstract
The present paper is dedicated to fabrication of microcellular PP-MMT nanocomposite foams blown by CO2 at 3-7 MPa pressure range. XRD and TEM studies showed that MMT particles were well exfoliated upon PP-MMT nanocomposite processing, however presence of the nanoclay particles did not facilitate the foaming process, resulting in non-uniform cell structure and low expansion ratios. SEM images demonstrate that clay nanoparticles have not improved the foam morphology; and no nucleation effect of the clay was observed in the produced foams. These data were supported by DSC studies.
References
1.
Suh K.W.
, Advanced Materials , 12 , (2000 ) 1779 –1789 .
2.
Kumar V.
, Cell. Polym. , 12 , (1993 ) 207 –223 .
3.
Arora K.A.
,
Lesser A.J.
, and
McCarthy T.J.
, Macromolecules , 31 , (1998 ) 4614 –4620 .
4.
Vanvuchelen J.
,
Perugini C.
,
Deweerdt M.
,
Chen L.
, and
Burnham T.
, J. Cell. Plast. , 36 , (2000 ) 148 –157 .
5.
Kumar V.
,
VanderWel M.
,
Weller J.
, and
Seeler K.A.
, Journal of Engineering Materials and Technology , 116 , (1994 ) 439 –445 .
6.
Zappala J.F.
, J. Cell. Plast. , 7 , (1971 ) 309 –312 .
7.
Doroudiani S.
,
Park C.B.
, and
Kortschot M.T.
, Polymer Engineering & Science , 36 , (1996 ) 2645 –2662 .
8.
Hamedi M.
,
Muralidharan V.
,
Lee B.C.
, and
Danner R.P.
, Fluid Phase Equilibria , 204 , (2003 ) 41 –53 .
9.
Zhang P.
,
Zhou N.Q.
,
Wu Q.F.
,
Wang M.Y.
, and
Peng X.F.
, Journal of Applied Polymer Science , 104 , (2007 ) 4149 –4159 .
10.
Zhai W.
,
Wang H.
,
Yu J.
,
Dong J.-Y.
, and
He J.
, Polymer , 49 , (2008 ) 3146 –3156 .
11.
Song G.
,
Yang S.
,
Yang C.
, and
She X.
, Journal of Porous Materials , 13 , (2006 ) 297 –301 .
12.
Park C.B.
,
Cheung L.K.
, and
Song S.W.
, Cell Polym. , 17 , (1998 ) 221 –251 .
13.
Huang H.-X.
, and
Wang J.-K.
, Journal of Applied Polymer Science , 106 , (2007 ) 505 –513 .
14.
Jiang X.-L.
, J. Cell. Plast. , 45 , (2009 ) 515 –538 .
15.
Park C.B.
,
Behravesh A.H.
, and
Venter R.D.
, Polymer Engineering & Science , 38 , (1998 ), 1812 –1823 .
16.
Naguib H.E.
,
Park C.B.
, and
Reichelt N.
, Journal of Applied Polymer Science , 91 , (2004 ) 2661 –2668 .
17.
Xu Z.-M.
, The Journal of Supercritical Fluids , 41 , (2007 ) 299 –310 .
18.
Antunes M.
,
Velasco J.I.
,
Realinho V.
, and
Solórzano E.
, Polymer Engineering & Science , 49 , (2009 ) 2400 –2413 .
19.
Velasco J.I.
,
Antunes M.
,
Realinho V.
, and
Ardanuy M.
, Polymer Engineering & Science , 51 , (2011 ) 2120 –2128 .
20.
Takada M.
, and
Ohshima M.
, Polymer Engineering and Science , 43 , (2003 ) 479 –489 .
21.
Chiou J.S.
,
Barlow J.W.
, and
Paul D.R.
, Journal of Applied Polymer Science , 30 , (1985 ) 3911 –3924 .
22.
Oda T.
, and
Saito H.
, Journal of Polymer Science Part B: Polymer Physics , 42 , (2004 ) 1565 –1572 .
23.
Zhang Z.
,
Nawaby A.V.
, and
Day M.
, Journal of Polymer Science Part B: Polymer Physics , 41 , (2003 ) 1518 –1525 .
24.
Varma-Nair M.
,
Handa P.Y.
,
Mehta A.K.
, and
Agarwal P.E.
, Thermochimica Acta , 396 , (2003 ) 57 –65 .
25.
Svoboda P.
,
Zeng C.
,
Wang H.
,
Lee L.J.
, and
Tomasko D.L.
, Journal of Applied Polymer Science , 85 , (2002 ) 1562 –1570 .
26.
Lee Y.H.
,
Park C.B.
,
Wang K.H.
, and
Lee M.H.
, J. Cell. Plast. , 41 , (2005 ) 487 –502 .
27.
Garg A.
,
Gulari E.
, and
Manke C.W.
, Macromolecules , 27 , (1994 ) 5643 –5653 .
