Advanced Thermal Characterization of Styrene-Butadiene-Styrene (SBS)– Modified Asphalt Binders at Various SBS Contents and Long-Term Aging Levels

Abstract

Styrene-butadiene-styrene (SBS) is an elastomeric copolymer that improves asphalt materials resistance to thermal and fatigue cracking. Different SBS-modified asphalt binders were evaluated by means of unmodulated and modulated differential scanning calorimetry (DSC) to determine their glass transition temperature (T_g), glass transition width (T_g,width), and the existence of crystallizable fractions in the base binders. Furthermore, to assess the impacts of different SBS content and long-term aging on asphalt binders’ thermal characteristics, this study used the thermogravimetric analysis (TGA) method in air and under nitrogen purge. This research aims to improve the understanding of the compatibility of SBS with various base binders and their impact on binder thermal characteristics at various aging levels. To be precise, this systematic study investigated SBS-modified binders at various SBS concentrations (0%, 2%, 4%), for three base binders across various pressure aging vessel conditioning at 20, 40, and 60 h. Additionally, these 27 binders were evaluated using Superpave performance grading (PG) standard tests and the Fourier-transfer infrared spectroscopy. Results suggest that long-term aging generally increases binder T_g, leading to stiffer binders, while the inclusion of higher SBS content was found to effectively lower T_g, thereby enhancing the flexibility and low-temperature performance of the binders. Additionally, SBS increases the T_g,_width reflecting the increased heterogeneity of the multiphase modified binders. Although aging is expected to increase the T_g,_width, the presence of higher SBS content helps stabilize the T_g,_width across aging levels. Finally, the rate of maximum degradation from TGA was found to be useful for quantitative analysis of SBS after calibration.

Keywords

differential scanning calorimetry (DSC)modulated differential scanning calorimetry (MDSC)styrene-butadiene-styrene (SBS)polymer-modified asphalt (PMA)

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