Review and recommended thermodynamic properties of FeCO 3

Abstract

An extensive review of entropy, enthalpy of formation and Gibbs energy of formation, heat capacity, aqueous solubility and solubility constant of FeCO₃ is given. A consistent set of thermodynamic properties for FeCO₃ and relevant aqueous species is selected and recommended for use. Speciation schemes for aqueous FeCO₃ are reviewed and evaluated. Issues related to supersaturation of FeCO₃ are discussed. Works on the thermal decomposition of FeCO₃ are presented and an overview of measured solubility and synthesis of FeCO₃ is given.

Keywords

FERROUS IRON CARBONITE SIDERITE STANDARD STATE PROPERTIES EQUILIBRIUM CONSTANT SOLUBILITY CARBON DIOXIDE CORROSION FILM

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References

Baylis

J. R.

: J. Indust. Eng. Chem., 1926 18, (4), 370–80.

Baylis

J. R.

: Water Works Eng., 1930 83 13–14; 31–32; 35–36.

Kooijmans

: GWF Gas Wasserf 1938 81 611–615; 628–633.

Riesenfeld

F. C.

and Blohm

C. L.

: Petrol. Refiner 1950 29, (4), 141.

Hackerman

S. N.

and Glenn

E.E.

Jr : J. Electrochem. Soc., 1953 100 339–344.

Sowards

D. M.

and Hackerman

: J. Electrochem. Soc., 1955 102 297–303.

de Waard

and Milliams

D. E.

: Proc. ist Int. Conf. on ‘The internal and external protection of pipes’ Durham, UK September 1975 University of Durham, Paper Fl; 1–8; X85—X87.

Jensen

D. L.

Boddum

J. K.

Tjell

J. C.

and Christensen

T. H.

: Appl Geochem., 2002 17, (4), 503–511.

Jensen

D. L.

: Environ. Sci. TechnoL 1998 32, (18), 2657–2664.

10.

Schwab

A. P.

and Lindsay

W. L.

: Soil Sci. Soc. Am. J., 1983 47, (2), 201–205.

11.

Flügge

: ‘Process of making ferrous carbonate’ US patent842452 1907.

12.

Hem

J. D.

: ‘Restraints on dissolved ferrous iron imposed by bicarbonate, redox potential, and pH’ US Geological Survey Water Supply 1960 Paper I459—B.

13.

Singer

P. C.

and Stumm

: J. Am. Water Works Assoc., 1970 62 198–202.

14.

Ghosh

M. M.

O'Connor

J. T.

and Engelbrecht

R. S.

: J. San. Eng. ASCE 1996 92, (1), 199–213.

15.

Stumm

and Singer

P. C.

: J. San Eng. ASCE 1966 92 120.

16.

Wersin

: ‘The Fe(II)-0O2-H20 system in anoxic natural waters: equilibria and surface chemistry’

PhD thesis

Swiss Federal Institute of Technology, Zürich

1990.

17.

Millero

F. J.

and Pierrot

: Aquat. Geochem., 1998 4, (1), 153–199.

18.

Tillmans

and Klarmann

: Angew. Chem., 1924 36 94–97; 103–104; 111–115.

19.

Ptacek

C. J.

and Blowes

D. W.

: ACS Symp. Sci., 1994 550, 172–189.

20.

Ptacek

C. J.

: ‘Experimental determination of siderite solubility in high ionic-strength aqueous solutions’

PhD thesis

University of Waterloo, Ontario, Canada

1992.

21.

Dresel

P. E.

: ‘The dissolution kinetics of siderite and its effect on acid mine drainage’

PhD thesis

Pennsylvania State University, University Park, PA, USA

1989.

22.

French

B. M.

: Am. J. Sci 1971 271, (1), 37–78.

23.

Weidner

J. R.

: Am. J. Sci., 1972 272, (8), 735–751.

24.

Rosenberg

P. E.

: Am. J. Sci., 1963 261 683–690.

25.

Marion

G. M.

Catling

D.C.

and Kargel

J.S.

: Geochim. Cosmochim. Acta 2003 67, (22), 4251–4266.

26.

Rau

G. H.

: Energy Conyers. Manag., 2004 45, (13-14), 2143–2152.

27.

Palandri

J. L.

and K:

Y.K.

Proc. 11th Int. Symp. on Water-rock interaction’ Vol. 1 567–571; 2004

London

Taylor & Francis Group.

28.

Sontheimer

Kolle

and Snoeyink

: Am. Water Works Assoc., 1981 73 572–579.

29.

Schmitt

: Proc. Conf. CORROSION/83 Paper43; 1983

Houston

TX, NACE.

30.

Eriksrud

and Sontvedt

: Proc. Conf. CORROSION/83 Paper44; 1983

Houston

TX, NACE.

31.

Dunlop

A. K.

Hassell

H. L.

and R:

P.R.

Proc. Conf. CORROSION/83, Paper 46; 1983

Houston

TX, NACE.

32.

Wieckowski

Ghali

Szklarczyk

and Sobkowski

: Electrochim. Acta 1983 28 (II) 1619.

33.

Deltombe

and Pourbaix

: Proc. 6th Meet. Int. Comm. Electrochem. Thermodynam. Kinet.124–132; 1955

London

Butterworths.

34.

Stumm

and Lee

G. F.

: Schweizerische Zeitschrift für Hydrologie 1960 22 295–319.

35.

Hem

J. D.

: In ‘Principles and application of water chemistry’, (ed. Faust

S. D.

and Hunter

J. V.

), 625; 1967

New York

John Wiley and Sons, Inc.

36.

Bruno

Wersin

Stumm

and Brandberg

: Geochim. Cosmochim. Acta 1992 56, (3), 1149–1155.

37.

Mishra

Al-Hassan

Olson

D. L.

and M:

M.M.

Corrosion 1997 53 (n)852–859.

38.

Dong

Nishimura

and Kodama

: in ‘Materials Research Society symposium proceedings’ Vol. 713 ‘Scientific basis for nuclear waste management XXV’ 105–112; 2002

Warrendale

PA, Materials Research Society.

39.

Johnson

M. L.

and B:

M.B.

Proc. Conf. CORROSION/91, Paper 268; 1991

Houston

TX, NACE.

40.

Tomson

M. B.

and L:

M.L.

Proc. Int. Symp. on ‘Oilfield chemistry’ 257–264; 1991

Anaheim

CA, SPE.

41.

Johnson

M. L.

: ‘Ferrous carbonate precipitation kinetics — a temperature ramped approach’

PhD thesis

Rice University, Houston, TX, USA

1991.

42.

van Hunnik

Pots

B. F. M.

and Hendriksen

E. L. J. A.

: Proc. Conf. CORROSION/96, Paper 6; 1996

Houston

TX, NACE.

43.

Wajon

J. E.

G.-E.

and Murphy

P. J.

: Water Res., 1985 19, (7), 831–837.

44.

Greenberg

J. L.

: ‘High temperature kinetics of precipitation and dissolution of ferrous carbonate’

MSc thesis

Rice University, Houston, TX, USA

1986.

45.

Greenberg

J. L.

and B:

M.B.

Int. Symp. on ‘Metals speciation, separation, and recovery’, (ed. Patterson

J. W.

), I-1/17; 1986

Chelsea

MI, Lewis Publication, Inc.

46.

Ogundele

G. I.

and EW. White: Corrosion 1986 42, (2), 71–78.

47.

Robert

D. B.

: Talanta 1991 38, (2), 205–211.

48.

Greenberg

J. L.

and Tomson

M. B.

: Appl. Geochem., 1992 7, (2), 185–190.

49.

Golubev

S. V.

Bénézeth

and Schott

: Geophys. Res. Abstr., 2007 9 04038.

50.

Dugstad

: Proc. Conf. CORROSION/98 Paper31; 1998

Houston

TX, NACE.

51.

Nesic

Si. S.

Nordsveen

Nyborg

and Stangeland

: Proc. Conf. CORROSION/01 Paper40; 2001

Houston

TX, NACE.

52.

Nordsveen

Nesic

Nyborg

and Stangeland

: Corrosion 2003 59, (5), 443–456.

53.

Sun

Chokshi

and Nesic

: Proc. Conf. CORROSION/05 Paper285; 2005

Houston

TX, NACE.

54.

Sun

Nesic

: Proc. Conf. CORROSION/06 Paper365; 2006

Houston

TX, NACE.

55.

Gulbrandsen

: Proc. Conf. CORROSION/07 Paper322; 2007

Houston

TX, NACE.

56.

Whitman

G. W.

Russell

R. P.

and Altieri

V. J.

: Indust. Eng. Chem., 1924 17, (7), 665.

57.

Leybold

: Angew. Chem., 1924 37 190–191.

58.

Leybold

: GWF Gas Wasserfach 1927 70 294–295.

59.

Crolet

J. L.

and P:

J.P.

Proc. Conf. CORROSION/93, Paper 102; 1993

Houston

TX, NACE.

60.

Haarberg

Jakobsen

J. E.

and Oestvold

: Acta Chem. Scand., 1990 44, (9), 907–15.

61.

Olsen

Lunde

and Dugstad

: Oil Gas1 1999 97 59–62.

62.

Dugstad

and Seiersten

: ‘pH-stabilisation, a reliable method for corrosion control of wet gas pipelines’ Paper87560; 2004

Aberden

SPE.

63.

Grauer

: ‘Solubility products of M(II) — carbonates’ PSI Bericht99–04; 1999

Villigen

Paul Scherrer Institute.

64.

Preis

and Gamsjager

: Phys. Chem. Chem. Phys., 2002 4, (16), 4014–4019.

65.

Robie

R. A.

and R:

D.R.

‘Thermodynamic properties of minerals and related substances at 298.15°K (25°C and one atmosphere (1.013 bars) pressure and at higher temperatures’, USGS B

1259

Government Printing Office

Washington, DC, USA

1968.

66.

Robie

R. A.

Hemingway

B. S.

and R:

J.R.

‘ Thermodynamic properties of minerals and related substances at 298.15 K and 1 bar (105 Pascals) pressure and at higher temperature’, USGS B 1452

Government Printing Office

Washington, DC, USA

1978.

67.

Robie

R. A.

and S:

B.S.

‘ Thermodynamic properties of minerals and related substances at 298.15 K and 1 Bar (10. 5 Pascals) pressure and at higher temperatures’, USGS B 2131

Government Printing Office

Washington, DC, USA

1995.

68.

Nordstrom

D. K.

Plummer

L. N.

Langmuir

Busenberg

May

H. M.

Jones

B. F.

and L:

D.L.

in ‘ Chemical modeling in aqueous system II, ACS symposium series’, (ed. Melchior

D. C.

and Bassett

R. L.

), Vol. 416 398–413; 1990

Washington

DC, American Chemical Society.

69.

Latimer

W. E.

: ‘The oxidation states of the elements and their potentials in aqueous solutions’2nd edn; 1952

Englewood Cliffs

NJ, PrenticeHall Inc.

70.

Langmuir

: US Geol. Surv. Prof Pap., 1969 650B 180–184.

71.

Bann

Knacke

and Kubaschewski

: ‘Thermochemical properties of inorganic substances’; 1977 Berlin Springer-Verlag.

72.

Martell

A. E:

and Smith

R. M.

: ‘ Critical stability constants 4: inorganic complexes ‘; 1976

New York

Plenum Press.

73.

Wagman

D. D.

Evans

W. H.

Parker

V. B.

Halow

Bailey

S. M.

and H:

R.H.

Selected values of chemical thermo-dynamic properties. Tables for elements 35 through 53 in the standard order of arrangement’, National Bureau of Standards technical note

270–4

US Government Printing Office

Washington, DC, USA

1969.

74.

Wagman

D. D.

Evans

W. H.

Parker

V. B.

Schumm

R. H.

Halow

and Bailey

S. M.

: J. Phys. Chem. Ref Data 1982 11, (2).

75.

Kelley

K. K.

and T:

C.T.

‘ Metal carbonates: correlations and applications of thermodynamic properties’, Bulletin 384, in ‘Contributions to the data on theoretical metallurgy IV’1–73; US Department of the Interior

Bureau of Mines

1935.

76.

Parker

V. B.

and Khodakovskii

I. L.

: J. Phys. Chem. Refer. Data 1995 24, (5), 1699–1745.

77.

Cox

J. D.

Wagman

D. D.

and Medvedev

V. A.

: ‘CODATA key values for thermodynamics’; 1989 New York Hemisphere Publishing Corp.

78.

Baes

C. F.

and E:

R.E.

‘The hydrolysis of cations’

226–237; 1976

New York

John Wiley.

79.

Anderson

C. T.

: J. Am. Chem. Soc., 1934 56 849.

80.

Robie

R. A.

Haselton

H. T.

and Hemingway

B. S.

: Am. Mineral., 1984 69, (3-4), 349–357.

81.

Kelley

K. K.

: ‘Contribution to the data on theoretical metallurgy. XIII High temperature heat content, heat capacity and entropy data for the elements and inorganic compounds’ Bureau of Mines Bulletin 584 US Government Printing Office

Washington, DC, USA

1960.

82.

Kalinkina

I. N.

: Soy. Phys. JETP 1963 16, (6), 1432.

83.

Kostryukov

V. N.

and NI. Kalinkina: Zhurnal Fizicheskoi Khimii 1964 38, (3), 780–781.

84.

Kalinkina

I. N.

and NV. Kostryukov: Fizika Tverdogo Tela (Sankt-Peterburg) 1966 8, (1), 176–180.

85.

Robie

R. A.

: ‘Heats and free energies of formation of troilite, herzenbergite, magnesite, and rhodochrosite calculated from equilibrium data’ US Geol. Survey Prof. 1965 paper 525—D65–72.

86.

Helgeson

D. C.

Delany

J. M.

Nesbitt

H. W.

and Bird

D. K.

: Am. J. Set A 1978 278A 1–229.

87.

Wagman

D. D.

Evans

W. H.

Parker

V. B.

Halow

Bailey

S. M.

and H:

R.H.

‘Selected values of Chemical Thermodynamic Properties. Tables of the first 34 elements in the standard order of arrangement’

National Bureau of Standards technical note 270–3

US Government Printing Office

Washington, DC, USA

1968.

88.

Tremaine

P. R.

Vonmassow

and Shierman

G. R.

: Thermochim. Acta 1977 19, (3), 287–300.

89.

Tremaine

P.R.

and LeBlanc

J.C.

: J. Solut. Chem., 1980 9, (6), 415442.

90.

Randall

and Frandsen

: J. Am. Chem. Soc., 1932 54, 47–54.

91.

Patrick

W. A.

and Thompson

W. E.

: J. Am. Chem. Soc., 1953 75 1184–1187.

92.

Larson

J. M.

Cerutti

Garber

H. K.

and Hepler

L. G.

: J. Phys. Chem., 1968 72 2902.

93.

Johnson

G.K.

and Bauman

J.E.

: Inorg. Chem 1978 17, (10), 2774–2779.

94.

Preis

and Gamsjager

: Monatshefte Fur Chemie 2001 132, (11), 1327–1346.

95.

Gamsjager

Konigsberger

and Preis

: Pure Appl. Chem., 1998 70, (10), 1913–1920.

96.

Holland

T. J. B.

and Powell

: J. Metam. Geol., 1990 8 89–124.

97.

Wilcox

D. E.

and Bromley

L. A.

: J. Indust. Eng. Chem., 1963 55, (7), 32–9.

98.

Reiterer

Johannes

Gamjäger

: Mikrochim. Acta 1981 1 63–72.

99.

Reiterer

: ‘Löslichkeitskonstanten und Freie Bildungsenthalpien neutralerÜbergangsmetallcarbonate’, PhDthesis, Montanuniversität Leoben 1980.

100.

Stubina

N.M.

and Toguri

J.M.

: Trans. ISS 1989 10 87–90.

101.

Chai

and Navrotsky

: Am. Mineral., 1994 79, (9), 921–929.

102.

Helgeson

H. C.

: Am. J. Sci., 1969 267 729.

103.

Smith

H. J.

: J. Am. Chem. Soc., 1918 40 879–883.

104.

Bardy

and Péré

: Tribune du CEBEDEAU 1976 387 75.

105.

Serebrennikov

V. S.

: Geochem. Int., 1977 14 925–945.

106.

Ptacek

C. J.

Reardon

E. J.

: Proc. 7th Int. Symp. on Water-rock interaction’181–183; 1992

Rotterdam

Balkema.

107.

Garber

J. D.

Perkins

R. S.

Vamshidhar

R. J.

and A:

R.A.

Proc. Conf. CORROSION/96, Paper 176; 1996

Houston

TX, NACE.

108.

Silva

C. A. R.

Liu

X. W.

and Millero

F. J.

: J. Solut Chem., 2002 31, (2), 97–108.

109.

Sun

Nesic

: Proc. Conf. CORROSION/04 Paper380; 2004

Houston

TX, NACE.

110.

Palmer

D. A.

and van

Eldik: Chem. Rev., 1983 83, (6), 651–731.

111.

Högfeldt

: ‘Stability constants of metal-ion complexes - part A: inorganic ligands’ IUPAC chemical data series Vol. 21; 1982

Oxford

Pergamon.

112.

Zhuk

N. P.

: Zhurnal Fizicheskoi Khimii 1954 28 1690–1697.

113.

Ghosh

M. M.

: in Aqueous-environmental chemistry of metals’, (ed. Rubin

A. J.

), 193–217; 1974

Ann Arbor

MI, Ann Arbor Science.

114.

Davies

C. W.

: J. Chem. Soc., 1938 2 2093–2100.

115.

Wersin

Charlet

Karthein

and Stumm

: Geochim. Cosmochim. Acta 1989 53 2787–2796.

116.

Fouillac

and Criaud

: Geochem. J., 1984 18 297–303.

117.

Langmuir

: ACS Symp. Ser., 1979 93 353–387.

118.

Stumm

and J:

J.J.

‘ Aquatic chemistry: chemical equilibria and rates in natural waters’ 3rd edn; 1996

New York

Wiley.

119.

Davies

D. H.

and TG. Burstein: Corrosion 1980 36, (8), 416–422.

120.

Sidgwick

N. W.

: ‘The chemical elements and their compounds’ Vol. II; 1952

Oxford

Oxford University Press.

121.

Thurmond

and Millero

F. J.

: J. Solut. Chem., 1982 11, (7), 447.

122.

Millero

F. J.

and Hawke

D. J.

: Marine Chem., 1992, 40, (1-2), 19–48.

123.

Grethe

Plyasunov

A. V.

and Spahiu

: in ‘Modelling in aqautic chemistry’325–426; 1997

Paris

OECD NEA.

124.

Plummer

L. N.

and Busenberg

: Geochim. Cosmochim. Acta 1982 46 1011–1040.

125.

Larson

T. E.

: in ‘Principles and application of water chemistry’, (ed. Faust

S. D.

and Hunter

J. V.

), 433; 1967

New York

John Wiley and Sons, Inc.

126.

Mattigod

S. V.

and Sposito

: Soil Sci Soc. Am. J., 1977, 41, (6), 1092–1097.

127.

Baes

C. F.

and Mesmer

R. E.

: Am. J. Sci., 1981 281 935–962.

128.

Sweeton

F. H.

and Baes

C. F.

Jr : J. Chem. Thermodyn., 1970 2, (4), 479.

129.

Turner

D. R.

Whitfield

and Dickson

A. G.

: Geochim. Cosmochim. Acta 1981 45 855–881.

130.

Emerson

: Geochim. Cosmochim. Acta 1976 40, (8), 925–934.

131.

Postma

: Am. J. Sci., 1982 282, (8), 1151–1183.

132.

Gamsjäger

and Reiterer

: Environ. Int., 1979 2 419–424.

133.

Gamsjäger

and Königsberger

: in ‘ The experimental determination of solubilities’, (ed. Hefter

G. T.

and Tomkins

R. T.

), 315; 2003

New York

Wiley.

134.

Klarmann

: Z. Angew. Chem., 1924 37, (34), 645–646.

135.

Müller

and Harant

: Berg und Huttenmannisches Jahrbuch 1935 83 93–102.

136.

Müller

and Henecka

: Z. Anorg. Al/gem. Chem., 1929 181 159–171.

137.

Dugstad

: Proc. Conf. CORROSION/92 Paper14; 1992

Huston

TX, NACE.

138.

Dugstad

and Dronen

P.-E.

: Proc. Conf. CORROSION/99, Paper 20; 1999

Huston

TX, NACE.

139.

Millero

F. J.

Wensheng

and Aicher

: Marine Chem., 1995 50, (1-4), 21.

140.

King

D. W.

: Environ. Sci. TechnoL 1998 32, (19), 2997–3003.

141.

Jimenez-Lopez

and Romanek

C. S.

: Geochim. Cosmochim. Acta 2004 68, (3), 557–571.

142.

Leussing

D. L.

and Kolthoff

I. M

: J. Am. Chem. Soc., 1953 75 2476.

143.

Shock

E. L.

Sassani

D. C.

Willis

Sverjensky

S. A.

: Geochim. Cosmochim. Acta 1997 61, (5), 907–950.

144.

Powell

H. E.

: ‘Thermal decomposition of siderite and consequent reactions’ Report of investigations 6643

US Bureau of Mines

1965.

145.

Gayer

K. H.

and Woontner

: J. Phys. Chem., 1956 60 1569–1571.

146.

Ehlert

and Hempel

: Z. Elektrochem., 1912 18 727.

147.

Lan

and Jia

: Xi'an Dizhi Xueyuan Xuebao 1996 18, (2), 80–86.

148.

Gould

F. T.

: ‘Ferrous carbonate’ US patent3416883 1968.

149.

Haehnel

: J. Prakt. Chem., 1924 108 187–193.

150.

Brauns

: ‘Chemische mineralogie’398; 1896

Leipzig

Tauchnitz.

151.

Lyden

: Suomen Kemistiseuran Tiedonantoja 1925 34 72–79.

152.

Teodorovich

G. I.

and Shvedova

T. M.

: Biull. Moskov. Obshchestva Ispytatelei Prirody, Otdel. Geol., 1960 35, (4), 100–104.

153.

Wells

R. C.

: ‘The fractional precipitation of som ore-forming compounds at moderate temperatures’ USGS B 609

Government Printing Office

Washington, DC, USA

1915.

154.

Konz

P. R.

: ‘Method of gas purification and removal of ferrous carbonate from the absorption solution’ US patent3264056 1966.

155.

Babcan

: Geol. Zborn. Geol. Carpath., 1974 25, (1), 53–63.

156.

Günzburg

: ‘Ober die Darstellung und die Eigenschaften von Ferrobikarbonatlösungen’

PhD thesis

Großherzoglich Technischen Hochschule Fridericiana, Karlsruhe

1911.

157.

Andersen

T. R.

and Valle

: Proc. Conf. CORROSION/93 Paper73 1993

Houston

TX, NACE.

158.

Berg

L. G.

, and Buzdov

K. A.

: Zhurnal Neorganicheskoi Khimii 1961 6 2003–2008.

159.

Reynolds

W. C.

: J. Chem. Soc. Trans., 1898 73 262–267.

160.

Rosenberg

P. E.

and Foit

F.F.

Jr : Geochim. Cosmochim. Acta 1979 43 951.

161.

Chai

and Navrotsky

: Am. Mineral., 1996 81 1141–1147.

162.

Davidson

P. M.

: Am. Mineral., 1994 79, (3-4), 332–339.

163.

Erdoe

and Altorfer

: Werkst. Korros., 1976 27, (5), 304–312.

164.

Al-Hassan

Mishra

Olson

D. L.

and MM. Salama: Corrosion 1998 54, (6), 480–493.

165.

Music

Nowik

Ristic

Orehovec

and Popovic

: Croat. Chem. Acta 2004 77, (1-2), 141–151.

166.

Kamolpornwijit

Liang

Moline

G. R.

Hart

and West

O. R.

: Environm. Sci Technol., 2004 38, (21), 5757–5765.

167.

de Marco

Jiang

Z.-T.

Pejcic

and Pionen

: J. Electrochem. Soc., 2005 152, (10), B389—B392.

168.

de Marco

Jiang

Z.-T.

John

Sercombe

and Kinsella

: Electrochim. Acta 2007 52, (11), 3746–3750.

169.

Xia

Chou

K. C.

and Szklarska-Smialowska

: Corrosion 1989 45, (8), 636–642.

170.

Berg

L. G:

, and Buzdov

K. A.

: Zhurnal Neorganicheskoi Khimii 1962 7 1773–1778.

171.

Babcan

: Geol. Zbornik. Geol. Carpath., 1970 21, (1), 89–97.

172.

Ehrhardt

Schober

H. C.

and Seidel

: Z. Anorg. Al/gem. Chem., 1980 465 83.

173.

Ehrhardt

Schweer

and Seidel

: Z. Anorg. Al/gem. Chem., 1980 462 185–198.

174.

Lemke

and Biltz

: Z. Anorg. Al/gem. Chem., 1934 220 312.

175.

Huxley

E. E.

and Fetchin

: ‘Process for producing ferrous carbonate and removing oil from ammonia therewith’, US patent 3058810 1962.

176.

Hoy

: ‘Improvements in the manufacture of iron carbonate’ GB patent7465 1899.

177.

Lilly

J. K.

: ‘Production of ferrous carbonate’ US patent876366 1908.

178.

Parker

C. L.

: ‘Improvements in & connected with the production of glauber salts, ferrous-carbonate, ferrous-hydrate & ammonia from nitre-cake’ GB patent24639 1903.

179.

Graf

D. L.

: Am. Mineral., 1961 46 1283–1316.

180.

Baudisch

and Web

L. A.

: J. Biol. Chem., 1925 64 753–770.

181.

Gill

: ‘Manufacture of ferric oxide’, US patent 842452 1911.

182.

Johannes

: Contrib. Min. Petrol., 1968 17, (2), 155–164.

183.

Sharp

W. E.

: Am. Mineral., 1960 45 241–243.

184.

Flügge

: ‘Pure ferrous carbonate’ Germany patent178878 1905.

185.

Gogolev

A. V.

Zakharova

E. V.

Rodygina

N. I.

Fedoseev

A. M.

and PV. Shilov: Radiochemistry 2006 48, (3), 249–253.

186.

Heuer

J.K.

and Stubbins

J.F.

: Corros. Sci 1999 41, (7), 1231–1243.

187.

Lyon

W. G.

: ‘Process for preparing ferrous carbonate’ US patent4657752 1987.

188.

Allison

C. F.

Dreher

G. M.

and AC. Trathowen: ‘Production of ammonium sulfate and ferrous carbonate from ferrous sulfate-containing solutions’, US patent 2845332 1958.

189.

Flügge

: ‘ Iron carbonate’, France patent FR 371876 1906.

190.

Flügge

: ‘An improvement of manufacture of ferrous carbonate in the cold’. GB patent 27316 1907.

191.

Gayer

K. H.

and Woontner

: J. Chem. Educ., 1957 34 178–179.