Simulations of long-term anaerobic corrosion of carbon steel containers in Canadian deep geological repository

Carbon steel is a candidate container material for the disposal of used fuel in a deep geological repository in sedimentary host rock in Canada. Prediction of the long term anaerobic corrosion behaviour of the container is important, not only because it partly determines the container lifetime but also because the products of the corrosion reaction, Fe(II) and H₂, can impact the properties of the clay based sealing materials and host rock. A mechanistically based numerical model is described that predicts both the long term corrosion rate and the effects on the repository environment, including the periodic build-up and release of H₂, the precipitation of Fe₃O₄ within the bentonite buffer, and the alteration of montmorillonite to a non-swelling clay. The results of a reference simulation for a repository in shale host rock are described.