Transient inclusion formation and evolution in silicon killed steels

Abstract

Transient inclusion formation in low carbon silicon killed steel as a result of ferroalloy additions of ferro-silicon (Fe75Si) and ferro-manganese (FeMn) (for de-oxidation and alloying) was studied in the laboratory using a novel experimental technique. Inclusion chemistries and morphologies were analysed using automated scanning electron microscopy (ASPEX). Formation of these inclusions was studied using thermodynamic software (FactSage) and a mechanism was proposed. Effect of solute concentration gradients during alloy dissolution and mixing was observed. Inclusions which formed initially, at low concentrations of ferroalloy, were liquid phase with a high concentration of FeO. Depending on the ferroalloy addition, initial inclusions become richer in SiO₂ or MnO. Inclusions also underwent further phase transformations on cooling.

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