Abstract
Radicals, derived from the ozonates of alkenes, have been shown to be capable of initiating polymerisations of methyl methacrylate, styrene and vinyl acetate: in the case of styrene polymerisations the molar masses obtained at low conversion did not follow the expected trend with temperature.
References
1.
Rimmer S.
, and
Ebdon J. R.
, J. Macromol. Sci.–Pure App. Chem. , 1995 , A32 , 831 .
2.
Lockley J.E.
,
Ebdon J. R.
,
Rimmer S.
, and
Tabner B. J.
, Polymer , 2001 , 42 , 1797
3.
Cunliffe D.
,
Lockley J. E.
,
Ebdon J. R.
,
Rimmer S.
, and
Tabner B. J.
, Macromol. 2001 , 34 , 3882 .
4.
Criegee V.R.
, Just. Lieb. Ann. Chem. , 1953 , 583 , 1
5.
Bauld N.C.
,
Thompson J. A.
,
Hudson C. E.
, and
Bailey P. S.
, J. Am. Chem. Soc. , 1968 , 90 , 1822 .
6.
Murray R.W.
, Acc. Chem. Res. , 1968 , 1 , 313 .
7.
Pryor W.A.
,
Gu J.-T.
, and
Church D. F.
, J. Org. Chem. , 1985 , 50 , 185 .
8.
Pryor W.A.
,
Ohto N.
, and
Church D. F.
, J. Am. Chem. Soc. , 1983 , 105 , 3614 .
9.
Qi B.
,
Zhang Y. H.
,
Shao K. S.
,
Tang X. Y.
, and
Hu M.
, Chemosphere , 1999 , 38 , 1213 .
10.
Lockley J.E.
,
Ebdon J. R.
,
Rimmer S.
, and
Tabner B. J.
, Macromol. Rap. Comm. , 2000 , 21 , 795 .