Syntheses and Characterisation of Amide Adducts of Uranyl Bis (β-Diketonates) the Molecular Structure of [UO 2 (DBM) 2 .C 4 H 9 CON( 3 -C 5 H 11 ) ( sec -C 4 H 9 )] †
Free accessOtherFirst published online August, 2003
Syntheses and Characterisation of Amide Adducts of Uranyl Bis (β-Diketonates) the Molecular Structure of [UO 2 (DBM) 2 .C 4 H 9 CON( 3 -C 5 H 11 ) ( sec -C 4 H 9 )] †
The first structurally characterised uranyl bis (β-diketonate)-amide adduct compound [UO2(DBM)2. C4H9CON (3-C5H11) (sec-C4H9)] (DBM = dibenzoylmethanate) shows that the amide ligand bonded through its amido oxygen atom to the uranyl group. The average bond distances for U–O(uranyl), U–O(DBM) and U–O(amide) are 1.778(5), 2.346(5) and 2.411(5)Å respectively.
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