The Brönsted Equation: The Universal Equation?

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The differences between homogeneous and heterogeneous catalysis are not always clear. Thus, in microheterogeneous systems like micellar and related systems, which can influence the rate of reactions, the distinction is not easy. In some sense, this depends on the point of view of the observer. If the system is considered monophasic, and the reactants and micelles are considered as solutes, micellar effects would be a special case of homogeneous catalysis. However, if the micellar system, with a solvent phase and a micellar phase, as is implicit in the pseudophase model, the micellar effects should be considered as heterogeneous catalysis.

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