We are interested in the connection between kinetic models with Fermi–Dirac statistics and fluid dynamics. We establish that moments and parameters of Fermi–Dirac distributions are related by a diffeomorphism. We obtain the macroscopic limits when the fluid is dense enough that particles undergo many collisions per unit of time. This situation is described via a small parameter ε, called the Knudsen number, that represents the ratio of mean free path of particles between collisions to some characteristic length of the flow. We give the conditions that allow us to formally derive the generalized Euler equations from the Boltzmann equation by adopting the formalism proposed in [Advances in Kinetic Theory and Continuum Mechanics, Springer, Berlin, 1991, pp. 57–71]. These conditions are related to the H-theorem and assume a formally consistent convergence for fluid dynamical moments and entropy of the kinetic equation. We also discuss the well-posedness of the obtained Euler equations by using Godunov’s criterion of hyperbolicity.
In this work we establish the connection between kinetic theory for Fermi–Dirac statistics and macroscopic fluid dynamics. We derive formal limits; in order to do that, we introduce a scaling for standard kinetic equation (see, for example, [12]) of the form
Here is a non-negative function representing the density of particles with position x and velocity v in the single-particle phase space at time t. The interaction of particles through collisions is given by the operator ; this operator acts only on variable v and is non-linear in the general case. We will keep this operator abstract.
We base the connection between kinetic and macroscopic dynamics on the conservation properties and entropy relations implying that the equilibria are Fermi–Dirac (i.e. of the form ) distributions.
It is important to notice that our approach differs from Hilbert expansion employed in works of C. Cercignani. Our results highlight the role of entropy as it was done in [1]; the convergence assumptions are similar to those in [3]. We also adopt the formalism for moments of distributions proposed in [2].
In the Section 4 we examine the moments of Fermi–Dirac distributions and establish that the parameters of such a distribution are related to the moments by a diffeomorphism. While in the case of Maxwellian distributions such a relation is rather evident, the case of Fermi–Dirac distributions requires an additional analysis.
We obtain the macroscopic limits when the fluid is dense enough that particles undergo many collisions per unit of time. In order to describe this situation, we introduce a small parameter ε, called the Knudsen number, that represents the ratio of mean free path of particles between collisions to some characteristic length of the flow.
Conservation properties are used to derive the compressible Euler equations from (1.1); we will do so in Section 6, assuming a formally consistent convergence for fluid dynamical moments and entropy of the kinetic Eq. (1.1) (see Theorem 5).
Kinetic models with Fermi–Dirac statistics
Denote for an integrable function s its moment .
We assume that for all measurable functions rapidly decaying on infinity
the collision operator C satisfies the conservation properties
corresponding to the conservation of mass, momentum and energy through the collision process. If we multiply Eq. (1.1) by 1, v, and integrate with respect to v, we obtain the respective local conservation laws:
We also assume that for every measurable rapidly decaying function F satisfying (2.1) the non-negative quantity
is the entropy production rate for this collision process.
Observe that
therefore multiplying both parts of Eq. (1.1) by and integrating with respect to v yields
which gives us a local entropy inequality
Finally, the equilibria are assumed to be characterized by zero entropy production rate and are given by the class of Fermi–Dirac distributions (for more information see, for example, [11])
We assume the following analogy of the Boltzmann’s H-theorem for the Fermi–Dirac statistics.
For every measurable rapidly decaying function F satisfying (2.1) with at most polynomially increasingthe following properties are equivalent:
Example of a collision operator for Fermi–Dirac statistics
In this section we give an example of a collision operator satisfying the conservation properties (2.2) and with positive entropy production rate (2.4) together with H-theorem.
Consider the operator studied in [5]:
where for
and – a collision kernel. Observe that the definition of vectors and implies the following relations:
Observe also that
The above expression allows us to take the collision kernel in the form
In order to prove that the operator C indeed satisfies the relations (2.2) and (2.4), we first establish the following proposition.
Suppose that we have functionsandsuch that the integralexists. Then the following identity holds:
We give the proof of this proposition in Appendix B.
The following proposition shows that the operator C indeed satisfies the conservation properties (2.2).
for any measurable function F rapidly decaying on infinity satisfying (2.1).
Take any function , . Let ; introduce a function
and observe that
for all . Applying Proposition 1 to W defined above and h we can conclude that
Since , applying the relation (3.2) yields
for all v, and ω. Therefore
and the proposition holds. □
For any measurable function F rapidly decaying on infinity satisfying (2.1) we have
We apply the Proposition 1 with W defined in (3.4) and and obtain that
Denote and , then we can rewrite the above expression as
The function is non-negative and so is the collision kernel b, therefore we can conclude that
□
(H-theorem).
For every measurable rapidly decaying F with at most polynomially increasingsatisfying (2.1) the following properties are equivalent:
If F is of the form (2.5), then
hence the entropy production rate is zero. On the other hand, by direct substitution one can show that in this case .
If the entropy production rate is zero, then applying the Proposition 1 with W defined in (3.4) and yields
Let for simplicity , then we can rewrite this expression as
Since the function is non-negative on and vanishes if and only if , we deduce that almost everywhere in v, or, in other words
By Boltzmann–Gronwall theorem (see, for example, [4,6,16]) this implies that
for some constants and . In its turn, this implies that G is a local Maxwellian distribution and therefore F is a local Fermi–Dirac distribution.
Finally, if ,
with . Since the factor is non-negative, we obtain that , which, as above, implies that G is a local Maxwellian distribution, and therefore F is a Fermi–Dirac distribution. □
Moments and parameters of Fermi–Dirac distributions
Recall the definition of Maxwellian distributions:
for parameters , , . Define the vector of moments for such a distribution:
It is easy to see that the space of possible moments is described by
Moreover, the map
is a diffeomorphism; indeed, the expression (4.1) clearly shows that is smooth. In addition, the same expression allows us to say that
hence the inverse application exists and is also smooth.
Another observation requires a slightly different parametrisation of a Maxwellian distribution. If
and if the moments are defined as
then the following equations hold:
This result quickly follows from the relations
The goal of this section is to establish the similar properties of moments of Fermi–Dirac distributions and find under which conditions the parameters of this distribution can be found via its moments.
We study the Fermi–Dirac distribution
The admissible parameters form an open convex set :
The moments of the distribution F are
Therefore, we can define a map
Let U be the range of , i.e. . We will examine the properties of U and establish that is a diffeomorphism . To simplify the calculations, we will introduce the following notations:
It is easy to see that
The quantities ρ and can be expressed in terms of polylogarithms assuming . We discuss the properties of these special functions in Appendix A.
The following theorem establishes the invertibility of the map .
If ρ andare given by (4.2) and (4.3), respectively, then the following statements hold:
the ratiodepends only on f,
setting, then the mapisand strictly monotone; there exists a function
the function θ is given by,
the mapis a diffeomorphism,
f and θ seen as functions of ρ andsatisfy
We can express ρ and in terms of polylogarithms:
with
which yields (1). Let
The expressions for moments together with properties of polylogarithms yield
As established in the Theorem A.1 (see Appendix A), the function is strictly monotone, hence the map is invertible. In order to obtain possible values of a, we study
The Taylor development of polylogarithms for writes (see, for example, [13–15])
in other words, near , which implies that
On the other hand, we know the limiting behaviour of polylogarithms when and (see, for example, [17]):
which yields
hence
Thanks to the monotonicity of the function , we obtain that . The regularity of the function follows from the regularity of polylogarithms; the expression for θ is a direct consequence of (4.7) and the previous point.
Finally, the following equations show that the map is invertible:
The differential Eqs (4.5) and (4.6) follow from (1) and (2), respectively. □
The inequality
comes from the form of Fermi–Dirac distributions; they are bounded by 1, therefore this inequality can be interpreted as that a Fermi–Dirac distribution cannot accumulate an arbitrary number of particles with small velocities in one point.
The result of the Theorem 2 allows us to say that the image of the map is a convex set
Indeed, U is the subset of above the graph of the function
The Hessian of h writes
By Sylvester’s criterion, this matrix is positive definite for ; hence, the function h is convex and, therefore, the set U is convex.
The entropy and the map
From now on we drop the subscript in the notation . We define the vector of conserved quantities as follows:
Let us define the operator ⊙ as the standard scalar product in . Then we can put every Fermi–Dirac distribution in the form
It is important to notice that does not depend on v.
One can easily see that the parameters of the representation (2.5) and are connected by
Let us consider the vector of conserved densities
Clearly, the image of the map is the set where U is defined in (4.10). The relations (5.1) and Theorem 2 imply that the map T is a diffeomorphism .
The following proposition establishes the form of entropy associated with the Fermi–Dirac distribution.
There exists a positive and strictly convex functionsuch thatforgiven by (5.2).
There exists a strictly convex functionsuch thatmoreover, this function is the entropy density of the Fermi–Dirac distribution associated with.
Put
then
Note that is a strictly positive and convex function of , because
is a positive definite matrix. Indeed, take a vector and suppose that
Since is positive, then for almost all v; the functions 1, , , and are linearly independent on , which results in . We can therefore conclude that is strictly convex.
Let the function σ be the Legendre transform of the function , then σ is also a convex function and
The function σ is defined on and can be expressed via the relation
with , so
In other words, this function coincides with the expression for the entropy density of the Fermi–Dirac distribution associated with . □
The following theorem establishes the form of the entropy flux associated with entropy density σ defined in Theorem 3.
The flux corresponding to the Fermi–Dirac distributionfor each,is a map, written asThere exists a functionsuch that
The functionfor everyanddefined byis the entropy flux for the Fermi–Dirac distribution associated with conserved densities.
The expression for quickly follows from the form of local conservation laws (2.3).
If
then
with . Indeed,
Consider the function given by
with . We can simplify it by writing
Since , we can further simplify as
We conclude that τ is the entropy flux of the Fermi–Dirac distribution associated with the conserved densities . □
Applications to the Eulerian limit
Assume that the collision operator satisfies properties (2.2), (2.4) and (2.6). We consider – a sequence of non-negative solutions ofsuch thatconverges to a non-negative function F almost everywhere inas ε tends to zero. Assume also that the momentsconverge in the sense of distributions to the corresponding momentsthat the entropy density and entropy flux converge in the sense of distributionsand finally that the entropy production rate satisfyThen the limit F is a local Fermi–Dirac distributionwhere the vector of conserved densitiessatisfies the system of conservation lawstogether with the entropy inequalityin the sense of distributions on.
Multiplying Eq. (6.1) by and integrating with respect to v gives
The left-hand side of the above expression tends to zero in the sense of distributions as ε tends to zero. On the other hand, , therefore it is a Radon measure. Hence,
In particular, this holds for , so
by Fatou’s lemma we conclude that
The characterisation of equilibria (3.5) allows us to say that for almost every the distribution F is a solution of and has therefore the form (2.5).
In the system of local conservation laws
we pass to the limit in the sense of distributions. Thanks to the convergence assumptions of this theorem, we obtain the compressible Euler system (6.2).
The right-hand side is non-positive by the characterization (3.5) and the left-hand side converges in the sense of distributions to , which yields (6.3). □
Observe that the system (6.2) has the convex entropy σ, therefore, it has Godunov’s structure and hence is hyperbolic (see, for example, [7–9] and [10]). The hyperbolicity of the system (6.2) implies several useful properties, notably that it has a unique smooth local solution.
Footnotes
Properties of polylogarithms
We study the polylogarithms for the argument defined by the formula
In order to simplify the reasoning, we introduce the notations
We will use the following properties:
;
for the function is positive and monotonically increasing. Moreover, as ;
if , then
If, then the functionis strictly positive.
For each fixed w, we examine the function
with
Clearly, we have for all , so that is defined for . By continuity, we can put .
Indeed, converges to as by Lebesgue theorem; on the other hand,
by the comparison test, which implies that
We want to prove that for .
Let us consider the function
We claim that this function is strictly log-convex. Indeed, , so is defined.
Let us take with and . By Hölder’s inequality,
hence
The inequality is strict because the functions and are linearly independent since .
Thus, the function is strictly convex. Clearly, this function is . In particular, the function
is strictly increasing wherever it is defined. Indeed, let us suppose that its derivative is zero at some point:
As , we conclude that on the interval , which contradicts the strict convexity of on its domain of definition, hence is strictly increasing. It follows immediately that Ψ itself is strictly increasing, which assures that on its domain of definition.
Thus, we conclude that has a strictly positive second derivative for . □
We also conjecture that is convex for , which is supported by numerical evidence and the fact that is a strictly convex function.
Technical result
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