In this article, we are interested in the study of the well-posedness as well as of the long time behavior, in terms of finite-dimensional attractors, of a coupled Allen–Cahn/Cahn–Hilliard system associated with dynamic boundary conditions. In particular, we prove the existence of the global attractor with finite fractal dimension.
In this article we consider the following Cahn–Hilliard/Allen–Cahn system with dynamic boundary conditions:
Here, , , is a smooth and bounded domain with boundary Γ corresponding to the binary material under consideration, u denotes the concentration of one of the components and is a conserved quantity, while v is an order parameter and μ represents the chemical potential. Furthermore, the parameter α reflects the location of the system within the phase diagram and may be either positive or negative. In what follows we consider, without any restriction of generality, α positive (the case α negative can be treated similarly, adapting certain a priori estimates). Moreover, δ, σ are nonnegative parameters related to the boundary diffusion and is a physical coefficient. Also, is the Laplace–Beltrami operator on Γ, is the outward normal derivative and the nonlinear function f is the derivative of a “bulk” double-well potential F. Finally, g is the derivative of a surface potential G and taken as an affine function. The evolution boundary value problem (1.1)–(1.6) is completed by the initial conditions and .
The Cahn–Hilliard/Allen–Cahn system (1.1)–(1.3) endowed with Neumann boundary conditions was introduced in [3,5] to model simultaneous order-disorder and phase separation in binary alloys on a BCC lattice in the neighborhood of the triple point. For further references on the physical pertinence of the model we refer the interested reader to [9]. The authors of [5] explored two phenomenological approaches leading to systems of coupled Allen–Cahn/Cahn–Hilliard (AC/CH) equations. Another important application of the coupled (AC/CH) equations is that under appropriate compositional conditions, ordering can be induced in a previously homogeneous material. If the composition differs slightly from these conditions, the excess composition can emerge as droplets along the boundaries between the ordered regions. This phenomena can be modeled by a coupled (AC/CH) system with degenerate mobilities. In similar applications, surface diffusion coupled with motion by mean curvature appears quite naturally. There are additional effects which are often neglected and which arguably should be included. However, the coupled motion, by itself, is not fully understood and it was thus reasonable to isolate it and study it, even given its limitations (see [8]).
In order to derive system (1.1)–(1.6), we consider the following Ginzburg–Landau free energy:
where is the surface gradient. Here, we will take the double-well potential F as the regular one defined by
i.e.,
We note that, in the Cahn–Hilliard theory, a thermodynamically relevant potential F is the following logarithmic function which follows from a mean-field model (see [23,24,27,30]):
Furthermore,
This logarithmic potential F is usually approximated by the regular one defined in (1.8). It should be noted that this approximation is acceptable when the absolute temperature θ is close to the critical one .
Furthermore, the function G is a surface potential, defined by
i.e.,
where accounts for a modification of the effective interaction between the components at the walls and b characterizes the possible preferential attraction of one of the components by the walls; when b vanishes, there is no preferential attraction (see [19]).
The first line in (1.7) is the Ginzburg–Landau (bulk) free energy, while the second one corresponds to the surface energy. Moreover, integrating (1.1) over Ω, we find, in view of (1.4),
so that we have the total (in the bulk and on the boundary) conservation of mass
Dynamic boundary conditions have been proposed by physicists, in the context of the Cahn–Hilliard equation, in order to account for the interactions with the walls in confined systems (cf. [10–12,19] and the references therein; see also [13] and [18] for permeable or non-permeable walls). In particular, such boundary conditions have mainly been studied for polymer mixtures (although this should also be important in other systems, such as binary metallic alloys): from a technological point of view, binary polymer mixtures are particularly interesting, since the structures occurring during the phase separation process may be frozen by a rapid quench into the glassy state; micro-structures at surfaces on very small length scales can be produced in this way.
The original Cahn–Hilliard system, endowed with dynamic boundary conditions, has been studied in [6,13–15,18,28,33,34], and [39] for regular potentials f and g. In particular, one now has satisfactory results on the existence, uniqueness and regularity of solutions and on the asymptotic behavior of the solutions. The case of logarithmic (and also more general singular) nonlinear terms has been treated in [16–18], and [30]. In that case, one feature of the problem is that we can have the nonexistence of classical (i.e., distributional) solutions.
In [3], the authors prove the well-posedness and the existence of maximal attractors and inertial sets (i.e., exponential attractors) of the coupled (AC/CH) system for the usual cubic nonlinear term in three space dimensions when Neumann boundary conditions are considered. We also refer the interested reader to [25] and [26], where the authors studied the asymptotic behaviour of the system, both for the regular and singular potential cases. The numerical study by a finite element approximation was treated in [2] for the case of a degenerate Allen–Cahn/Cahn–Hilliard system under Neumann boundary conditions.
A similar system, with a non-constant mobility, was treated in [7] where the existence of weak solutions for the Neumann problem for a degenerate parabolic system consisting of a fourth-order and a second-order equation with singular lower-order terms in one space dimension was proved. In addition, asymptotics for a similar system with a non-constant mobility, proposed as a diffuse interface model for simultaneous order-disorder and phase separation, was studied in [31]. There, A. Novick–Cohen focused on the motion in the plane. This framework yields both sharp and diffuse interface models of sintering of small grains and thermal grains boundaries grooving in polycrystalline films. This work was extended in [32], where the authors studied the partial wetting case, and their analysis accounts for motion in three space dimensions.
We also mention that several numerical methods were used in order to solve coupled (AC/CH) systems; see, e.g., [5,22,35,37,38,40]. Furthermore, a Newton–Krylov–Schwarz (NKS) method for the implicit solution of a coupled (AC/CH) system was studied in [41] and very recently, the coupled Cahn–Hilliard/Allen–Cahn system endowed with dynamic boundary conditions (1.1)–(1.6) has been studied numerically in [21], in which the authors obtained error estimates between the exact and the approximated solution and prove the stability of a fully discrete scheme based on the backward Euler scheme for the time discretization.
This article is organized as follows. In Section 2, we introduce our main assumptions and notations, together with a number of tools which are needed in order to reformulate system (1.1)–(1.6). Then, in Section 3, we give the functional setting of our system. In Section 4, we derive a priori estimates, which allow us to prove in Section 5 the existence of solutions; the uniqueness is obtained by classical arguments, following [4]. In Section 6, we obtain-higher order estimates to get further regularity on the solution. Finally, adapting the proof introduced by S. Zelik in [42], in Section 7 we prove the existence of the global attractor which has finite fractal dimension.
The main technical difficulty of this work is due to the presence of dynamic boundary conditions which requires the adaptation of classical techniques in order to study the existence and uniqueness of the solutions in certain function spaces, as well as the asymptotic behavior of the model. The proofs of existence and uniqueness, as well as higher regularity of solutions, are based on a classical Galerkin approximation and a priori estimates that allow the passage to limit; we refer the interested reader to [20] and [36] for further reading. The proofs in Section 7 are based on analytical tools introduced by [1,36] and further developed by [29,42] in order to prove the existence of a global attractor of finite fractal dimension in the context of partial differential equations.
Notations and assumptions
First, we set and denote by the scalar product on and by the related norm. Moreover, we set and denote by the (topological) dual of . The duality between and is indicated by .
We also set and and denote by the standard scalar product in , by the corresponding norm, and by the duality between and . In general, indicates the norm in the generic (real) Banach space X and stands for the duality between and X.
We can then define the Hilbert spaces
endowed with the natural scalar products and norms. Unless otherwise specified, in what follows, we will impose the following convention: when we write , h will be interpreted as a pair of functions belonging, respectively, to and to . Analogously, when we consider (or even ), the symbol ρ will be intended, depending on the context, either as a function defined in Ω, or as a pair formed by a function in Ω and its trace on Γ.
We also define, for ,
We then set
In particular, the norm on is equivalent to the usual -norm.
We need some further discussion on the functional spaces.
We first notice that we have the chain of continuous embeddings
Indeed, it is not difficult to prove that the space is dense in .
Next, we introduce the elliptic operators
defined as
where , for . The operators are positive, self-adjoint and unbounded linear operators. Furthermore, we can define the domain of in ,
Finally, noting that can be considered as a self-adjoint and compact operator on , we can define the powers , together with their domains (keeping in mind that ), so that , can be extended as an isomorphism from onto and, more generally from onto . Following exactly the same arguments as in [24] (see Proposition 5.3), one can show that and the norm is equivalent to the usual -norm on .
Furthermore, for , the embedding is continuous. Also, the norm is equivalent to the usual -norm on .
Noting that, by definition , we see that the embedding is continuous and the norm is equivalent to the usual -norm on .
Finally, we note that . Furthermore, since the norm is equivalent to the -norm, it follows that the norm is equivalent to the usual -norm on .
We refer the interested reader to [24] for more details and proofs.
As far as the nonlinear terms f and g defined in (1.9) and (1.13) are concerned, we note that they satisfy the following properties:
where and the constants , depend continuously on m.
Throughout this paper, the same letter c (and, sometimes, ) denotes constants which may change from line to line, or even in a same line.
Functional setting of the problem
Using the function spaces and the operators introduced in the previous section, we can rewrite (1.1)–(1.6) in the following functional form:
where, with an abuse of notation,
and we defined
with .
Setting, whenever it makes sense,
so that , we can rewrite (3.1) in the equivalent form
noting that .
Therefore, we can write the initial value problem in the following functional form:
where
In what follows we will actually consider initial data in (see Theorem 5.1), so that the trace indeed makes sense.
A priori estimates
In this section we derive a priori estimates, based on which we can prove the existence and uniqueness of solutions.
First, we take the scalar product in of (3.5) by . We get, noting that ,
We also take the scalar product in of (3.6) by to obtain
Combining (4.1) and (4.2), we get
We take the scalar product in of (3.7) by to have
Summing (4.3) and (4.4), we obtain
Next, we take the scalar product in of (3.5) by and find
Taking the scalar product in of (3.6) by U, we get
Thus, we have
We then take the scalar product in of (3.7) by V and obtain
Summing (4.8) and (4.9), we find, owing to (2.2)–(2.3)
We now assume that
Thanks to the conservation of mass (1.14), assumption (4.11) implies that , . The purpose of this assumption will become clearer in Section 7 and more exactly in Theorem 7.1, where one can see that the existence of a global attractor holds on the subspace of of functions of total mass equal to M.
Therefore,
We thus deduce from (4.10) and (4.12) that
where by we denote a constant depending on M that may change at different places in the text.
Combining now (4.5) and (4.13), we have a differential inequality of the form
where
satisfies
Next, we take the scalar product in of (3.5) by and, noting that , we find
We then take the scalar product in of (3.7) by to obtain
Summing (4.17) and (4.18), we find
Furthermore, recalling that and g is affine, we have, using (2.1)
Similarly, we have
We finally obtain
Rewriting (3.5) in the equivalent form
we have the following estimate:
Noting that, proceeding as in (4.12),
we finally find
which implies that .
Existence of solutions
In what follows we prove the following existence and uniqueness result:
We assume that. Then, (
3.5
)–(
3.8
) possesses a unique weak solutionsuch thatand
Existence: The proof of existence of a solution is based on the a priori estimates derived in the previous section and e.g., a standard Galerkin scheme. In particular, it follows from (4.14), (4.16) and Gronwall’s lemma, that we can construct a sequence to a proper approximated problem such that
It follows from (5.1), (5.2) and the Aubin–Lions compactness theorem that
The strong convergence given by (5.3) also implies that
which allows us, using classical arguments, to pass to the limit in the nonlinear terms.
Uniqueness: Let and be two solutions of (3.5)–(3.8) with initial data and , respectively, such that . Set
and
Then, satisfies
Taking the scalar product in of (5.5) by , we get
We note that and , since .
We can now take the scalar product in of (5.6) by U and have
We thus obtain
Take now the scalar product in of (5.7) by V to have
Let and . We have
where and are some appropriate linear combinations of p and q.
Proceeding similarly, we obtain
Therefore, using the previous inequalities, equation (5.12) yields
Employing the interpolation inequality
we deduce that
It finally follows from Gronwall’s lemma that
whence the uniqueness, as well as the continuous dependence with respect to the initial data in the -norm. □
Further regularity results
The purpose of this section is to obtain higher-order a priori estimates on the solution of the Cahn–Hilliard/Allen–Cahn system.
Thanks to the regularity (4.24), we know that and . We deduce that , . Furthermore, since g is affine and , then
Next, owing to the continuous embedding and as f is a cubic potential, we have that
Noting that
we thus see that
which yields, employing Agmon’s inequality , that
Thanks to (4.24), we obtain
Using the elliptic regularity result in [28], we deduce that
Now, we have
and thus, by elliptic regularity, we obtain
Having these regularity estimates, we now differentiate with respect to time the following equations for and V, respectively:
and we find
where
and
Taking the scalar product in of equations (6.8) and (6.9) by and , respectively, we have
which yields, owing to (2.1) and employing the interpolation inequality
the differential inequality
Therefore, owing to (4.14), we can apply the uniform Gronwall lemma to (6.11) and we obtain that
Now, we return to (3.3), which we write in the following form:
The elliptic regularity result in [28] yields that
Next, owing to Hölder’s inequality, the continuous embedding , and the interpolation inequality , we have
and similarly we can have
We note that here we have used the fact that
Therefore,
Now, as g is affine, we get
Let us now note that (3.5) and (6.12) imply
We have, in view of (3.6),
Using the Sobolev embedding valid on both two and three dimensional spaces, we also know that
and thus . Therefore,
Writing (3.6) as
and using , we see that . Taking into account the elliptic regularity, we finally obtain that
We thus deduce that
Consequently, the equations
make sense in .
We have thus proved the following regularity result:
Let the assumptions of Theorem
5.1
hold. Then we haveandfor alland. Furthermore, the problem written under the differential operator formmakes sense in.
Existence of global attractors
In what follows, we intend to prove the existence of global attractors for the CH/AC system. The techniques used are classical and are based on the existence of absorbing sets in suitable function spaces. For more details on the subject, we refer the interested reader to [1,29] and [36].
Using Theorem 5.1, let us first define the continuous semigroup
where
This family of operators forms a semigroup (i.e., , where I denotes the identity operator, and ).
Furthermore, it follows from (5.17) that we can extend, in a unique way and by continuity, this semigroup to
It is then standard to prove the following result:
The semigrouppossesses the global attractoronfor the-topology which is bounded in.
It follows from (4.14) and Gronwall’s lemma that we have
which yields that
Thus, is dissipative in in the sense that it possesses a bounded absorbing set . Assume now that belongs to a ball centered at zero and of radius R, given, i.e., . Then, since the embedding is continuous, belongs to a bounded set in . Thus, there exists such that implies . It then follows from (4.13) that
and
where the (positive) constants c depend only on and on M. We can then apply the uniform Gronwall lemma to (4.14) to deduce that
where the constant c depends only on and M. It follows from (7.5) that the semigroup is dissipative in i.e., it possesses a bounded absorbing set in which is compact in .
Thus, using Theorem 2.35 in [24], we prove the existence of the global attractor in . □
We now give the following definition:
Let be a relatively compact set. For , let be the minimal number of balls in E of radius ε which are necessary to cover X. Then, the fractal dimension of X is the quantity (which belongs to )
Furthermore, the quantity is called the Kolmogorov ε-entropy of X.
We then give the following general result for proving the finite fractal dimensionality of a compact set (see [42]):
Let X be a compact subset of E. We assume that there exists a Banach space, with norm, such thatis compactly embedded in E and a mappingsuch thatand L satisfies the following smoothing property on the difference of two solutions:Then, the fractal dimension of X is finite and satisfieswhereis the unit ball in(note that it is relatively compact in E, so thatis finite).
We now prove the finite fractal dimensionality of the global attractor using Theorem 7.2:
The global attractorhas finite fractal dimension for the topology of.
We consider two solutions and to the problem with initial data and , respectively, belonging to . We have, setting and (note that ),
First, proceeding as in the proof of uniqueness in Theorem 5.1, we obtain
It follows from Gronwall’s lemma that
which yields
Next, taking the scalar product in of (7.8) by , we find
Taking then the scalar product in of (7.9) by , we have
Summing (7.13) and (7.14), we obtain
Furthermore,
and similarly
We now have
where is an appropriate linear combination of , , , .
Concerning the first term on the right-hand side, we see that
Using the interpolation inequality , we see that
and thus
Concerning the second term on the right-hand side of (7.18), we proceed similarly,
We thus obtain
and, similarly,
with . Since g is affine, we get
and
Furthermore,
and, similarly,
We have
Noting that , we see, owing to the triangular inequality in and the continuous embedding , that
Thus,
and, similarly,
Therefore, gathering all these estimates, we obtain
where
with
since thanks to Theorem 5.1.
Thus, denoting
we obtain the following differential inequality:
where . In particular,
Using Gronwall’s lemma, it follows that
and, taking , we have
From (7.12), we also obtain
Consequently,
and we conclude the proof, thanks to Theorem 7.2 with . □
Footnotes
Acknowledgement
The authors wish to thank an anonymous referee for her/his careful reading of the manuscript and many useful comments which helped improve it.
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