Waste Management & Research: The Journal for a Sustainable Circular Economy

This study reports the use of sewage sludge generated from sewage treatment plant (STP) as raw material in a clay brick-making process. The physico-chemical and mineralogical characterization of the sewage sludge and clay were carried out in order to identify the major technological constraints and to define the sludge pretreatment requirements if necessary. Moreover, the effects on processing conditions and/or on changes of typical final characteristics are also evaluated. Bricks were produced with sewage sludge additions ranging from 10 to 40% by dry weight. The texture and finishing of the surface of sludge-amended clay bricks were rather poor. As for the physical and chemical properties, bricks with a sludge content of up to 40 wt.% were capable of meeting the relevant technical standards. However, bricks with more than 30 wt.% sludge addition are not recommended for use since they are brittle and easily broken even when handled gently. A tendency for a general degradation of brick properties with sludge additions was observed due to its refractory nature. Therefore, sludge bricks of this nature are only suitable for use as common bricks, which are normally not exposed to view, because of poor surface finishing.

The aim of this study was to develop cost-effective, appropriate solidification technologies for treating hazardous industrial wastes that are currently disposed of in ways that may threaten the quality of local groundwater. One major objective was to use materials other than cement, and preferably materials that are themselves wastes, as the solidification additives, namely using wastes to treat wastes or locally available natural material. This research examines the cement-based and lime-based stabilization/solidification (S/S) techniques applied for waste generated at a metal-plating industry and a dye industry. For the lime-based S/S process the following binder mixtures were used: cement kiln dust/lime, bentonite/lime and gypsum/lime. For the cement-based S/S process three binder mixtures were used: cement kiln dust/cement, bentonite/cement and gypsum/cement. The leachability of the wastes was evaluated using the toxicity characteristic leaching procedure. The applicability and optimum weight ratio of the binder mixtures were estimated using the unconfined compressive strength test. The optimum ratio mixtures were mixed with waste samples in different ratios and cured for 28 days in order to find the S/S products with the highest strength and lowest leachability at the same time. The results of this work showed that the cement- and lime-based S/S process, using cement kiln dust and bentonite as additives can be effectively used in order to treat industrial waste.

Implementation of stricter environmental laws and economic reasons has forced all the metallurgical industries to go for eco-friendly technologies to produce metal and other related products. However, generation of wastes is an integral part of metallurgical industries. If the wastes/residues are hazardous in nature, they generally have to be treated or/and disposed of in safe and designated dumping sites. If these wastes/residues are non-hazardous in nature, then they may be suitable for use as secondary raw material to recover metals such as lead, copper etc., which are in growing demand all over the world. The processing of lead secondaries is important because of their relative high metal content, as well as the low energy and cost involved in recovering the metal. This paper mainly focuses on the current practices and recent trends in the secondary processing of lead. Various processes, particularly hydrometallurgical ones, already developed or in the development stages, are discussed. Attempts made by various Council of Scientific and Industrial Research (CSIR) Laboratories including the National Metallurgical Laboratory (NML) and industries such as Binani Zinc to develop eco-friendly processes for the recovery of lead from secondary raw materials are also described.

Almost all metallurgical processes are associated with the generation of wastes and residues that may be hazardous or non-hazardous in nature depending upon the criteria specified by institutions such as the US Environment Protection Agency, etc. Wastes containing heavy and toxic metals such as arsenic, cadmium, chromium, nickel, lead, copper, mercury, zinc, etc., that are present beyond permissible limits deemed to be treated or disposed of, and non-hazardous wastes can be utilized for metal recovery or safe disposal. Zinc is in growing demand all over the world. In India, a major amount of zinc is imported and therefore processing of zinc secondaries will assist in satisfying the gap between demand and supply to some extent. This report mainly focuses on the current practices and recent trends on the secondary processing of zinc. Attempts made by various laboratories to develop ecofriendly processes for the recovery of zinc from secondary raw materials are also described and discussed.

The fine particle size fraction of municipal solid waste incinerator bottom ash is often problematic because reuse applications for this material are limited. In these experiments incinerator bottom ash with a particle size of less than 8 mm was processed using conventional ceramic production techniques involving wet milling, drying, compacting and sintering. The effect of sintering temperature on the sintered density, microstructure, acid neutralization capacity (ANC) and the release of metal ions as a function of leachate pH are reported. Sintering at 1080 °C produced samples with maximum density. This material contained diopside (CaMgSi₂O₆), clinoenstatite (Mg₂Si₂O₆) and wollastonite (CaSiO₃) as the major crystalline phases. The acid neutralization capacity of sintered samples is significantly lower than milled bottom ash, and further reduces as the sintering temperature increases. This is associated with reduced leaching of Ca from sintered ash samples under all leachate pH conditions. Heavy metals present in the incinerator bottom ash included Cr, Cu, Ni, Zn, Cd and Pb. Sintering under optimum conditions reduced the leachable fraction of these metals under aggressive acid conditions (leachate pH 3) by factors ranging from 90% for Ni to greater than 99% for Cr, Cd, Zn and Pb.

Coal-fired power plants all over the world are cited as one of the major sources that generate huge quantities of coal combustion residues (CCRs) as solid wastes. Most frequently CCRs are collected through electrostatic precipitators, mixed with bottom ash by hydraulic systems and deposited in ash ponds. The quality of the CCRs at different locations in one of the ash ponds in Central India was evaluated to understand the variation in characteristics with a view to effective utilization. Results revealed that the presence of fine particles (< 50 μm) increased with increasing distance from the ash slurry inlet zone in the ash pond. Wide variations in the bulk density (800-980 kg m^-3), porosity (45-57%) and water-holding capacity (57.5-75.7%) of CCRs were recorded. With increasing distance the pH of the CCRs decreased (from 9.0 to 8.2) and electrical conductivity increased (from 0.25 to 0.65 dS m^-1). The presence of almost all the heavy metals in CCRs exhibited an increase with distance from the ash slurry discharge zone due to the increase in surface area (from 0.1038 to 2.3076 m² g^-1) of CCRs particles. The present paper describes the variation of characteristics of CCRs deposited in the ash pond and their potential applications.

The degradation of fats during thermophilic composting was investigated by adding lard of four different mixing ratios (0, 33.3, 42.9 and 50% on a dry weight basis) to dog food used as a model substrate for organic waste. The lard added at the mixing ratio of 33.3% did not inhibit the decomposition of organic matter in the dog food, with lard itself beginning decomposition after decay of more easily decomposable organic compounds of the dog food, 84 h from the start of composting. The percentage of lard decomposition reached as high as 29.3% by the end of 8 days of composting. By contrast, the decomposition of organic matter in the processed dog food was apparently inhibited when the portion of lard was greater than 33.3%, especially at the earliest stage of composting. It is possible, however, that lard would decompose vigorously once decomposition has begun, even when the ratio of lard is as high as 50%. The percentages of lard decomposition in composting mixtures with 42.9 and 50% lard were 15.7 and 9.50%, respectively, thus the higher the mixing ratio of lard, the lower the percentage of lard decomposition. However, it was found that the maximum decomposition rate of the lard was similar for all of the ratios tested; that is, approximately 5.0 × 10^-3 g carbon h^-1.

Solid waste management presses for effective landfill design and operation. While planning and operating a landfill (LF) or a landraise (LR), choices need to be made regarding: (1) LF-LR morphology (base shape, side slopes, final cover thickness, LR/LF height/depth); (2) cell geometry (height, length, slopes); and (3) operation parameters (waste density, working face length, cover thicknesses). These parameters affect LF/LR capacity, operation lifespan and construction/operation costs. In this paper, relationships are generated between capacity (C, space available for waste) and the above parameters. Incorporating real data into simulation runs, two types of functions are developed: first, C = k _γ A ^1.38, where A is the LF/LR base area size and k _γ a base shape-dependent coefficient; and second, C = α_{p,γ, A}+ δ_{p,γ, A} X _p for every parameter p, where X _p is the value of p and α_{p,γ, A} and δ_p,γ,A are parameter-and base (shape/size)-specific coefficients. Moreover, the relationship between LF depth and LR height that balances excavation volume with cover material, is identified. Another result is that, for a symmetrical combination of LF/LR, with base surface area shape between square and 1: 2 orthogonal, and final density between 500 and 800 kg m^-3, waste quantity placed ranges from 1.76A ^1.38 to 2.55A ^1.38 tons. The significance of such functions is obvious, as they allow the analyst to investigate alternative LF/LR schemes and make trade-off analyses.

The use of poplar tree systems (PTS) as evapotranspiration barriers on decommissioned landfills is gaining attention as an option for leachate management. This study involved field-testing the Simultaneous Heat and Water (SHAW) model for its ability to reliably estimate poplar transpiration, volumetric soil water content, and soil temperature at a landfill located in southern Ontario, Canada. The model was then used to estimate deep drainage and to ascertain the influence of a young PTS on the soil water balance of the landfill cover. The SHAW model tended to underestimate poplar transpiration [mean difference (MD) ranged from 0.33 to 3.55 mm on a daily total basis] and overestimate volumetric soil water content by up to 0.10 m³ m^-3. The model estimated soil temperature very well, particularly in the upper 1 m of the landfill cover (MD ranged from -0.1 to 1.6 ×°C in this layer). The SHAW model simulations showed that deep drainage decreased appreciably with the presence of a young PTS largely through increased interception of rainfall, and that PTS have a good potential to act as effective evapotranspiration barriers in northern temperate climate zones.

Municipal solid waste management (MSWM) in the United States is a system comprised of regulatory, administrative, market, technology, and social subcomponents, and can only be understood in the context of its historical evolution. American cities lacked organized public works for street cleaning, refuse collection, water treatment, and human waste removal until the early 1800s. Recurrent epidemics forced efforts to improve public health and the environment. The belief in anticontagionism led to the construction of water treatment and sewerage works during the nineteenth century, by sanitary engineers working for regional public health authorities. This infrastructure was capital intensive and required regional institutions to finance and administer it. By the time attention turned to solid waste management in the 1880s, funding was not available for a regional infrastructure. Thus, solid waste management was established as a local responsibility, centred on nearby municipal dumps. George Waring of New York City organized solid waste management around engineering unit operations; including street sweeping, refuse collection, transportation, resource recovery and disposal. This approach was adopted nationwide, and was managed by City Departments of Sanitation. Innovations such as the introduction of trucks, motorized street sweepers, incineration, and sanitary landfill were developed in the following decades. The Resource Conservation and Recovery Act of 1976 (RCRA), is the defining legislation for MSWM practice in America today. It forced the closure of open dumps nationwide, and required regional planning for MSWM. The closure of municipal dumps caused a ‘garbage crisis’ in the late 1980s and early 1990s. Private companies assumed an expanded role in MSWM through regional facilities that required the transportation of MSW across state lines. These transboundary movements of MSW created the issue of flow control, in which the US Supreme Court affirmed the protection of garbage under the Commerce Clause of the Constitution. Thus MSWM in America today is largely managed by municipalities, and operated by a relatively small number of private companies. It consists of a mixture of landfill, incineration, recycling, and composting, and is regulated under RCRA, the Clean Air Act and other related federal and state laws.