Abstract
In order to improve structural fire-resistant behaviors, this paper designed a two-layer functionally graded ultra-high performance concrete (FGUHPC) structure composed of a UHPC layer and a lightweight aggregate concrete (LWAC) layer. UHPC layers are adopted to provide structural bearing capacity and protected by LWAC layers from elevated temperature. Splitting tensile tests and three-point flexural tests were conducted under ambient and elevated temperatures to evaluate interfacial bond performance and flexural bearing capacity, where two interfacial treatments were adopted and compared. The experimental results revealed that FGUHPC members exhibited good integrity during heating, no explosive spalling occurred and the maximal temperature at interfacial regions was 266°C. The interfaces showed desirable bond performance under ambient temperature while the splitting tensile strength was decreased by around 85% in the case of high temperature. Flexural test results indicated that the structural stiffness would be reduced by around 42% under elevated temperature, as a result, the maximal deflection was increased from 2.5 mm to 3.7 mm. SWM could significantly improve interfacial bond performance and prevent debonding failure of specimens at the postfire state, leading to higher structural bearing capacities. The bearing capacities of specimens with and without interfacial treatments were 42.7 kN and 38.4 kN respectively under ambient temperature, which remained about 88% after elevated temperature.
Keywords
Introduction
Ultra-high performance concrete (UHPC) has been proven as a class of cementitious material capable of addressing a variety of needs in structural engineering (Graybeal et al., 2020). Compared with normal concrete (NC), it provides better strength, durability, energy absorption and fatigue behavior (Yoo and Yoon, 2016), these advantages can lead to economical construction by saving material and installation costs (Abbas et al., 2016). However, UHPC is usually deemed as an undesirable fire-resistant material due to the occurrence of explosive spalling subjected to elevated temperature, which hinders its applications under fire risk (Liang et al., 2018). Two theories were commonly accepted as the explanations for the phenomenon, named thermal stresses theory and pore pressure theory respectively. Thermal stresses theory is related to the thermomechanical process, a steep thermal gradient would be developed due to the rapid increase of temperature, as a result, the high thermal stress between heated surfaces and moisture clogs is generated, leading to the spalling of UHPC (Li and Zhang, 2021). Pore pressure theory involves the low permeability and the absence of capillary pores of UHPC. High pore pressure would be induced in the case of vaporization in moisture clogs and the thermal dilation of vapor, therefore, the explosive spalling would occur as the pore pressure exceeds the tensile strength of concrete (Kodur and Banerji, 2021; Peng et al., 2017b). It shall be noted that the fire-induced spalling is a complex phenomenon, and could be influenced by many factors, such as heating regimes, moisture contents, aggregate sizes and types, and so on (Banerji et al., 2020; Zhu et al., 2021).
Functionally graded concrete (FGC) is a cementitious composite whose material composition is spatially varied by two or several mixes (Torelli et al., 2020), as Figure 1 shows. Layered graded concrete refers to material with a step-wise spatial in composition, while continuously graded concrete is defined as concrete with a continuously variable composition. Layered graded concrete is more common and easy to prepare, which has attracted much attention by researchers. In comparison, most studies of continuously graded concrete were based on finite element analyses (Herrmann and Sobek, 2017; Strieder et al., 2018), it is because the inherent limitations in production technologies shall be overcome to translate the concepts into practice, and recent improvements of robotics promote the development of manufacturing techniques for continuously graded concrete members. By reasonably adopting multiple materials in different structural regions, the overall or local performance would be effectively improved with lower cement consumption, self-weight and long-term costs. For instance, Bajaj et al. (2013) developed a two-layered functionally graded concrete beam (FCB) composed of NC and fly ash concrete layers, where the structural compressive and flexural strength were 12.86% and 3.56% higher than those of conventional NC members respectively. Maalej et al. (2003) aimed at improving the structural corrosion durability, to this end, a two-layered FCB was designed, where the ductile fiber reinforced cementitious composite material was employed as the bottom layer. In this way, the proposed FGB had a noticeably higher durability than normal beams, where the time to achieve the same level of steel corrosion was enhanced by about 70%. Liu et al. (2018) assessed the potential of FGB that using recycled aggregates in place of a part of natural aggregates for environmental purposes. The results revealed that the maximal cost and CO2 emission were reduced by 33.6% and 37.7% respectively compared with the traditional homogeneous material members. It is noticed that most of the studies aim at improving structural performances under ambient temperature, by contrast, there are few researches related to elevated temperature were reviewed. It is attributed to the incompatible deformation at interfacial regions between two materials subjected to high temperature, which might lead to delamination or debonding of interfaces (Shen et al., 2008). Zhang et al. (2022) established finite element models of a three-layer FCB, where the bond performance and flexural properties were discussed. According to the numerical results, the authors believed that the delamination failure could be avoided when the interfacial cohesive stiffness was higher than three. Du et al. (2023) designed a two-layered FGC member composed of UHPC layers and LWAC layers, debonding tests were conducted to evaluate the interfacial bond performance under different temperatures (20°C–1200°C), besides, the effect of cast-in bolts on bond strength were investigated. The results revealed that the bond strength was dramatically decreased with temperature, after 1200°C heating, the residual bond strength was reduced by around 95% compared with that under ambient temperature. The maximal improvement of bond strength was 56.5% when employing cast-in bolts, however, the effect became insignificant under high temperature due to the severe deterioration of LWAC, in this case, all specimens presented brittle failure. Nematzadeh and Mousavi (2021) studied the flexural behavior of FCB containing recycled tire crumb rubber under high temperature, where the effects of layers, fiber volume fractions, volume percentages of the rubber and heating regimes were discussed. The results indicated that the flexural capacity and stiffness of FGB were slightly increased under 300°C and markedly decreased by a range of 38% to 60% under 600°C. Layered and continuous functionally graded concrete.
Based on the FGC theory, a novel functionally graded ultra-high performance concrete (FGUHPC) was designed in this study. The structure is divided into two layers, including a UHPC layer and a lightweight aggregate concrete (LWAC) layer. UHPC layers are used to provide structural overall bearing capacities, stiffness, ductility and durability. LWAC, which is a desirable thermal insulation material with low thermal conductivity and good spalling resistance, is adopted as the protection layer from high temperature (Felicetti et al., 2013; Hassanpour et al., 2012), as Figure 2 diagrams. By this means, both the advantages of UHPC in mechanism and LWAC in thermology would be exploited. The structural self-weight and cross-sectional dimensions can be significantly decreased owing to the reduction of cement and reinforcement consumption (Nes and Overli, 2016), furthermore, extra fire protection techniques, such as insulation boards or coatings, could be removed. Configuration of FGUHPC.
This study aimed at evaluating the postfire performance of FGUHPC members in two aspects, including interfacial bond performance and flexural bearing capacity. To this end, splitting tensile tests and three-point flexural tests were conducted under both ambient and elevated temperatures, where two interfacial treating methods were adopted and compared. The interfacial temperature and spalling conditions were recorded and observed during the tests. The failure modes, loads, deflections, concrete strain and crack widths were measured and analyzed. Finally, the residual bearing capacities of FGUHPC members after fire were discussed and compared between the specification and experimental results.
Materials and experimental program
Mixture design and material properties
Mix proportions of UHPC and LWAC.
The dry premix was firstly mixed for 3 min, and the water with superplasticizers was then added and mixed for 5 min. Afterwards, the fibers were added and mixed until the mixtures were homogeneously mixed. Slumps were tested before casting according to GB 50204 (2015), where those of UHPC and LWAC were 63±3 cm and 47±3 cm respectively.
The mechanical and thermal properties of two materials were measured according to GB/T 50081 (2019) and GB/T 10294 (2008). The compressive strength, tensile strength, elastic modulus and thermal conductivity were tested by 100 mm×100 mm×100 mm cubes, 100 mm×100 mm×500 mm dog bones, 100 mm×100 mm×300 mm prisms and 250 mm×250 mm×50 mm plates respectively. Electro servo-hydraulic pressure testing systems were adopted for measuring mechanical properties, where the load rates for testing compressive strength, tensile strength and elastic modulus elastic were 1.0 MPa/s, 0.2 mm/min and 1.2 MPa/s respectively. The thermal conductivity was tested by a conductivity tester. Each group was tested by three samples, the results are presented and summarized in Figure 3 and Table 2 respectively. Tests on mechanical and thermal properties. Mechanical and thermal properties.
Specimen design and preparation
Splitting tensile tests and three-point flexural tests were conducted by 100 mm × 100 mm × 100 mm cubes and 150 mm × 150 mm × 550 mm prisms respectively. Both the thickness of UHPC layers and LWAC layers were 50 mm respectively for cubes while those of prisms were 100 mm and 50 mm in height respectively, as Figure 4 presents. The steel wire mesh (SWM) method was adopted to enhance the roughness of interfaces (Lu et al., 2022). SWM was pressed into the surfaces of concrete after casting and removed after hardening, the textures were shown at surfaces and the fibers were observed. Meanwhile, the specimens without interfacial treatments were also prepared as a contrast. Dimensions of specimens.
The LWAC layers were firstly cast, and the SWM treatment were subsequently conducted on the surfaces, after curing for 2 days, UHPC was cast against the hardened LWAC layers. All specimens were cured by 90°C steam for 2 days, afterwards, they were demolded and placed in a curing room until the follow-up process. Taking the cubes as an example, the casting procedure is exhibited in Figure 5. Casting procedure of FGUHPC members.
Experimental program
A 350 mm × 350 mm × 600 mm furnace was used for heating, and a steel cage was employed to prevent the furnace from damage caused by the explosive spalling of concrete, as Figure 6 shows. A severe heating regime was adopted in the tests, where the heating rate was 100°C/min to 1200°C and then kept at this temperature till 120 min. Bottom LWAC surfaces were regarded as the exposed surfaces, while the other surfaces were coated with fire retardant coatings in order to simulate one-side heating for both cube and prism specimens. For prism specimens, type K thermocouples were mounted at the depth of 50 mm (interfaces) from the exposed surface to determine the interfacial temperature. An electro servo-hydraulic pressure testing system with a load capacity of 300 kN. For the splitting tensile tests, the load was applied by 0.05 MPa/s and the strength Testing diagrams and measuring point arrangements.

Summaries of experimental specimens.
Note: AT: ambient temperature; HT: high temperature.
Experimental results
Overall performance
Temperature-time curves of the furnace and interface were recorded and depicted in Figure 7, in which the maximal temperature at the interface was 266°C. No noise was heard during the heating for all specimens, and no explosive spalling was observed at exposed surfaces. The bottom surfaces of LWAC turned yellow, where many cracks distributed. UHPC layers kept in good condition, no visible cracks and spalling were observed since they were at a relatively low temperature with the protection of LWAC layers. Temperature distributions and experimental phenomena.
For the cube specimens, obvious cracks along with interfaces were observed for the specimen without interfacial treatments (S-0-HT), and a part of specimens were broken apart directly, which was deemed as failure under high temperature. It is because of the discrepancy of expansion coefficients between two materials under high temperature, which would result in the interlaminar shear and incompatible deformation between two layers (Gao et al., 2019). In comparison, the specimens treated by SWM (S-SWM-HT) showed significantly better bond performance and no debonding occurred in spite of the small cracks at interfacial regions. For the prism samples, owing to larger contact areas, both F-SWM-HT and F-0-HT remained desirable bond behavior although visible cracks were observed at some of interfacial regions, as Figure 7 presents.
Results of splitting tensile tests
Splitting tensile test results.
Note: COV: coefficient of variation.

Results of splitting tensile tests.
In the case of high temperature, the splitting tensile strength was dramatically dropped, where the mean strength of S-SWM-HT and S-0-HT was 0.91 MPa and 0.37 MPa, approximately 15.3% and 8.0% of that under room temperature respectively. With the load increased, brittle fracture along with the interfaces suddenly occurred, leading to the failure of specimens. There was no crack developing process, and interfaces had become the weak zone at this time, as Figure 8 diagrams. Furthermore, high temperature would result in large scatters of the splitting tensile strength, where the variable coefficients of S-SWM-HT and S-0-HT were 23.85% and 15.29% respectively.
Results of three-point flexural tests
The load-deflection and load-strain curves are illustrated in Figures 9 and 10 respectively, where the details are summarized in Table 5. It is noted that the strain of LWAC bottom (0 mm) for specimens under high temperature was not recorded since the surface had been severely deteriorated at this moment. F-SWM-AT and F-0-AT exhibited similar overall performance under ambient temperature. At the initial state, two specimens presented similar stiffness, cracks were observed at the bottom of LWAC layers at a very early time, where the crack loads were 7.1 kN and 6.2 kN for F-SWM-AT and F-0-AT respectively. It is because LWAC had very low elastic modulus and tensile strength. With the load continued to increase, cracks developed upwards along with the mid-span, and the sound of steel fibers being pulled out was heard, leading to the ductile failure of specimens. F-SWM-AT showed slightly higher ultimate load, where the ultimate load and deflection were 42.7 kN and 2.6 mm, in comparison, those of F-0-AT were 38.4 kN and 2.4 mm respectively. Besides, the specimen treated by SWM exhibited higher stiffness, which was 9.4% higher than the sample without interfacial treatments. Load-deflection curves. Load-strain curves. Summaries of testing results. Note: 

Stress redistributions were observed for both specimens during the tests, as Figures 9 and 10 diagram. They occurred at the load of about 35 kN, indicating the total fracture of LWAC layers, and all loads were bore by UHPC layers at this time. As a result, the strain of UHPC rapidly increase, and the load continued to rise after a sudden drop. Major cracks along the mid-span location were observed, the cracks crossed interfaces continuously while no debonding or delamination between layers was detected, as Figure 11 shows. Phenomena of three-point flexural tests.
In the case of high temperature, LWAC layers had been severely damaged during heating, where a large number of visible cracks were observed. In this case, LWAC might no longer provide bearing capacities and no stress redistribution was observed from experimental results. Compared with ambient temperature, the stiffness of specimens subjected to elevated temperature was decreased by 41.7% to 43.4%, leading to greater deflections under the same load. F-SWM-HT remained good integrity during the test and showed flexural failure, however, for F-0-HT, interfacial debonding occurred due to the weakness of interfacial bond strength, leading to the occurrence of debonding failure, as Figure 11 diagrams. The ultimate loads of F-SWM-HT and F-0-HT were 37.6 kN and 33.9 kN respectively, 88.1% and 88.3% of those under ambient temperature. Besides, it was observed that the cracks were not continuous at interfaces. The maximal crack widths of LWAC layers of F-SWM-HT and F-0-HT were 3.8 mm and 4.5 mm respectively, significantly larger than those under ambient temperature while the discrepancies of crack widths of UHPC layers among specimens were not evident, as Table 5 lists.
Discussions
Mechanism of interfacial bond performance
This section discusses the mechanism of interfacial bond performance of FGUHPC members and the reason for the dramatic drop after high temperature. The interfacial bond strength between layers is mainly provided by two parts, one is the mechanical force, including bite force between layers and the bridging effect of fibers crossing interfaces, the other is the chemical bond force (van der Waals force) among molecules in the transition interfacial layer between two materials (Gao et al., 2019). UHPC contains a large number of active admixtures whose main components are SiO2 and Al2O3, they can absorb Ca(OH)2 to produce C-S-H gel, promote the hydration of C3S and C2S and reduce the water contents in pastes, as a result, the concentration of pastes is increased and the chemical bond force between layers will be improved. Meanwhile, the C-S-H gel can penetrate into gelled pores, which is beneficial to enhance the interfacial roughness (Graybeal et al., 2017). Besides, fibers crossing interfaces could contribute to the bond strength through the bridging effect. All these factors provide FGUHPC members high interfacial bond strength under room temperature, and specimens with SWM treatments presented slightly higher bond strength owing to higher mechanical bite force caused by rougher interfaces (Semendary and Svecova, 2021). It is concluded that there is no interfacial bond issue for FGUHPC elements under room temperature even if the interfaces were not treated on purpose.
In the case of elevated temperature, fibers have been melted, and Ca(OH)2 is decomposed into CaO and H2O, water in concrete has been evaporated, which increases the pore-water pressure in the matrix (Way and Wille, 2016). The transition layers would be damaged, resulting in the reduction or loss of the bond strength. Besides, the different thermal expansions between two materials may lead to an incompatible deformation and interlaminar shear at interfacial regions during heating, further reducing the bond strength. As a result, mechanical bite force becomes the main factor for the interfacial bond strength. In the test, the splitting tensile strength of specimens after heating was reduced by 85% and 92% respectively. Compared with specimens without interfacial treatments, SWM could slightly improve the bond strength by increasing the roughness of interfaces (Farzad et al., 2019).
Residual bearing capacities of FGUHPC members
The mechanical properties of UHPC show a tendency that first increase and then decline with temperature (Abid et al., 2017; Peng et al., 2017a). Based on the previous studies, the residual compressive strength, tensile strength and elastic modulus of UHPC under different temperatures had been tested, where the relative results are depicted in Figure 12. They increase with temperature before 200°C and decrease followed by. In the case of 400°C, the compressive strength of UHPC is almost the same with that under room temperature while the tensile strength and elastic modulus remain about 67% and 60% respectively. During the tests, the maximal temperature of UHPC layers was 266°C. Considering the excess temperature transferred from LWAC layers, the temperature of UHPC might continue to rise slightly after heating (Liu et al., 2023). In this case, UHPC would exhibit comparable compressive strength and lower tensile strength and elastic modulus, leading to a slight reduction of bearing capacity whereas a significant drop of stiffness compared with ambient temperature. Relative mechanical properties of UHPC after high temperature.
Assuming that the cross-sections of FGUHPC elements are satisfied with the plane section theory, hence the flexural bearing capacities under ambient temperature can be predicted by equaling LWAC layers to UHPC layers under the same flexural stiffness (Herrmann and Sobek, 2017), where the reduction factor Strain and stress profiles of FGUHPC elements.

The nominal flexural bearing capacity is calculated by T/CCPA 35-2022 (2022), namely the technical specification for UHPC structures:
It shall be noted that the contribution of longitudinal reinforcing bars is ignored in equation (3) and equation (4) since there are no longitudinal reinforcing bars in the tests.
Flexural strength of experimental results and specification.
Note:
Conclusions
This study aimed at improving structural fire-resistant performances and postfire behaviors. To this end, a two-layered functionally graded ultra-high performance concrete (FGUHPC) member was designed, and its interfacial bond and flexural performance subjected to ambient and elevated temperatures were evaluated by splitting tensile tests and three-point flexural tests respectively. The effects of two interfacial treating methods on interfacial bond performance were discussed. Based on the experimental results, the following conclusions can be drawn: 1. The designed FGUHPC elements exhibited desirable fire resistance, all specimens exhibited good integrity and no explosive spalling of UHPC occurred during 1200°C heating for 2 hours. The temperature at interfaces was 266°C, in this case, the mechanical properties of UHPC were not deteriorated owing to the thermal insulation of LWAC layers. 2. There was no interfacial bond issue for all specimens under room temperature. However, the splitting tensile strength was reduced by 85% to 92% under high temperature, SWM would efficiently improve the bond performance and prevent debonding failure of specimens. The stiffness and bearing capacity of the specimen treated by SWM was 9.4% and 11.2% higher than that without interfacial treatments. 3. At the postfire state, FGUHPC specimens showed lower stiffness, lower ultimate loads and larger deflections than those under ambient temperature. The reductions of structural stiffness and bearing capacity at ultimate state were around 42% and 12% respectively while the average deflection was increased from 2.5 mm to 3.7 mm. 4. The bearing capacities of FGUHPC members showed good agreement between experiments and the specification under room temperature. However, in the case of high temperature, the residual bearing capacities based on the experimental results were higher than those calculated by the specification. It might be because the mechanical properties of UHPC could be enhanced by elevated temperature within a limit.
Footnotes
Declaration of Conflicting Interests
The author(s) declared no potential conflicts of interest with respect to the research, authorship, and/or publication of this article.
Funding
The author(s) disclosed receipt of the following financial support for the research, authorship, and/or publication of this article: This study was supported by the National Natural Science Foundation of China (grant numbers: U1934205) and Academician special project of China Communications Construction Company (YSZX-01-2022-02-B).
